{"_buckets": {"deposit": "3b2aea9f-9197-44c5-9f79-f8d8d261e390"}, "_deposit": {"id": "16421", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "16421"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00016421"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2007", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "B67", "bibliographicPageStart": "B63", "bibliographicVolumeNumber": "154", "bibliographic_titles": [{"bibliographic_title": "Journal of The Electrochemical Society"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "An anhydrous proton conductor, 10mol% In^3+ -doped SnP2O7 (Sn0.9In0.1P2O7) , was composed by 1,8-bis(triethoxysilyl)octane (TES-Oct) and 3-(trihydroxysilyl)-1-propanesulfonic acid ((THS)Pro-SO3H) and was characterized by structural and electrochemical analysis. The composite membrane with 90wt% Sn0.9In0.1P2O7 showed high proton conductivities of 0.04Scm^\u22121 or more between 150 and 200\u00b0C in unhumidified air. The packing of the Sn0.9In0.1P2O7 particles in the matrix was relatively uniform, with no formation of pinholes observed. Fuel cell tests verified that the open-circuit voltage was maintained at a constant value of \u223c970mV regardless of the electrolyte thickness (60\u2013200\u03bcm) , while the Ohmic resistance was decreased to 0.24\u03a9cm2 by reducing the electrolyte thickness to 60\u03bcm . The peak power densities achieved with unhumidified H2 and air were 109mWcm^\u22122 at 100\u00b0C , 149mWcm^\u22122 at 150\u00b0C , and 187mWcm^\u22122 at 200\u00b0C . Furthermore, fuel cell performance was improved by hot-pressing an intermediate layer consisting of Sn0.9In0.1P2O7 , Pt/C , TES-Oct, and (THS)Pro-SO3H between the electrolyte and cathode.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://dx.doi.org/10.1149/1.2388737"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/18430"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "The Electrochemical Society"}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u00a9 The Electrochemical Society, Inc. 2006. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in Journal of The Electrochemical Society. v.154, n.1, 2007, p.B63-B67."}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0013-4651", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Heo, Pilwon"}], "nameIdentifiers": [{"nameIdentifier": "49117", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nagao, Masahiro"}], "nameIdentifiers": [{"nameIdentifier": "49118", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kamiya, Toshio"}], "nameIdentifiers": [{"nameIdentifier": "49119", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sano, Mitsuru"}], "nameIdentifiers": [{"nameIdentifier": "49120", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tomita, Atsuko"}], "nameIdentifiers": [{"nameIdentifier": "49121", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hibino, Takashi"}], "nameIdentifiers": [{"nameIdentifier": "49122", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-02-20"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "J_Electrochem_Soc_2007-Heo-B63-7.pdf", "filesize": [{"value": "403.1 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 403100.0, "url": {"label": "J_Electrochem_Soc_2007-Heo-B63-7.pdf", "url": "https://nagoya.repo.nii.ac.jp/record/16421/files/J_Electrochem_Soc_2007-Heo-B63-7.pdf"}, "version_id": "85a8880b-c92c-4a53-b79d-b1cbe00350c8"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "tin compounds", "subitem_subject_scheme": "Other"}, {"subitem_subject": "indium compounds", "subitem_subject_scheme": "Other"}, {"subitem_subject": "organic-inorganic hybrid materials", "subitem_subject_scheme": "Other"}, {"subitem_subject": "membranes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "electrochemical analysis", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ionic conductivity", "subitem_subject_scheme": "Other"}, {"subitem_subject": "solid electrolytes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "electrical resistivity", "subitem_subject_scheme": "Other"}, {"subitem_subject": "hot pressing", "subitem_subject_scheme": "Other"}, {"subitem_subject": "proton exchange membrane fuel cells", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Sn0.9In0.1P2O7-Based Organic/Inorganic Composite Membranes : Application to Intermediate-Temperature Fuel Cells", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Sn0.9In0.1P2O7-Based Organic/Inorganic Composite Membranes : Application to Intermediate-Temperature Fuel Cells"}]}, "item_type_id": "10", "owner": "1", "path": ["488/489/490"], "permalink_uri": "http://hdl.handle.net/2237/18430", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2013-08-28"}, "publish_date": "2013-08-28", "publish_status": "0", "recid": "16421", "relation": {}, "relation_version_is_last": true, "title": ["Sn0.9In0.1P2O7-Based Organic/Inorganic Composite Membranes : Application to Intermediate-Temperature Fuel Cells"], "weko_shared_id": null}