{"_buckets": {"deposit": "3b2aea9f-9197-44c5-9f79-f8d8d261e390"}, "_deposit": {"id": "16421", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "16421"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00016421", "sets": ["490"]}, "author_link": ["49117", "49118", "49119", "49120", "49121", "49122"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2007", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "B67", "bibliographicPageStart": "B63", "bibliographicVolumeNumber": "154", "bibliographic_titles": [{"bibliographic_title": "Journal of The Electrochemical Society", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "An anhydrous proton conductor, 10mol% In^3+ -doped SnP2O7 (Sn0.9In0.1P2O7) , was composed by 1,8-bis(triethoxysilyl)octane (TES-Oct) and 3-(trihydroxysilyl)-1-propanesulfonic acid ((THS)Pro-SO3H) and was characterized by structural and electrochemical analysis. The composite membrane with 90wt% Sn0.9In0.1P2O7 showed high proton conductivities of 0.04Scm^−1 or more between 150 and 200°C in unhumidified air. The packing of the Sn0.9In0.1P2O7 particles in the matrix was relatively uniform, with no formation of pinholes observed. Fuel cell tests verified that the open-circuit voltage was maintained at a constant value of ∼970mV regardless of the electrolyte thickness (60–200μm) , while the Ohmic resistance was decreased to 0.24Ωcm2 by reducing the electrolyte thickness to 60μm . The peak power densities achieved with unhumidified H2 and air were 109mWcm^−2 at 100°C , 149mWcm^−2 at 150°C , and 187mWcm^−2 at 200°C . Furthermore, fuel cell performance was improved by hot-pressing an intermediate layer consisting of Sn0.9In0.1P2O7 , Pt/C , TES-Oct, and (THS)Pro-SO3H between the electrolyte and cathode.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://dx.doi.org/10.1149/1.2388737"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/18430"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "The Electrochemical Society", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1149/1.2388737", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "© The Electrochemical Society, Inc. 2006. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in Journal of The Electrochemical Society. v.154, n.1, 2007, p.B63-B67.", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0013-4651", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Heo, Pilwon", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "49117", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nagao, Masahiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "49118", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kamiya, Toshio", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "49119", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sano, Mitsuru", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "49120", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tomita, Atsuko", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "49121", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hibino, Takashi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "49122", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-02-20"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "J_Electrochem_Soc_2007-Heo-B63-7.pdf", "filesize": [{"value": "403.1 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 403100.0, "url": {"label": "J_Electrochem_Soc_2007-Heo-B63-7.pdf", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/16421/files/J_Electrochem_Soc_2007-Heo-B63-7.pdf"}, "version_id": "85a8880b-c92c-4a53-b79d-b1cbe00350c8"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "tin compounds", "subitem_subject_scheme": "Other"}, {"subitem_subject": "indium compounds", "subitem_subject_scheme": "Other"}, {"subitem_subject": "organic-inorganic hybrid materials", "subitem_subject_scheme": "Other"}, {"subitem_subject": "membranes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "electrochemical analysis", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ionic conductivity", "subitem_subject_scheme": "Other"}, {"subitem_subject": "solid electrolytes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "electrical resistivity", "subitem_subject_scheme": "Other"}, {"subitem_subject": "hot pressing", "subitem_subject_scheme": "Other"}, {"subitem_subject": "proton exchange membrane fuel cells", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Sn0.9In0.1P2O7-Based Organic/Inorganic Composite Membranes : Application to Intermediate-Temperature Fuel Cells", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Sn0.9In0.1P2O7-Based Organic/Inorganic Composite Membranes : Application to Intermediate-Temperature Fuel Cells", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["490"], "permalink_uri": "http://hdl.handle.net/2237/18430", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2013-08-28"}, "publish_date": "2013-08-28", "publish_status": "0", "recid": "16421", "relation": {}, "relation_version_is_last": true, "title": ["Sn0.9In0.1P2O7-Based Organic/Inorganic Composite Membranes : Application to Intermediate-Temperature Fuel Cells"], "weko_shared_id": -1}