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Steady chirality conversion by grinding crystals : Supercritical and subcritical bifurcations
http://hdl.handle.net/2237/20566
http://hdl.handle.net/2237/205667d2d6e0c-c557-4996-a5f9-b9ecd7d72964
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2014-09-25 | |||||
タイトル | ||||||
タイトル | Steady chirality conversion by grinding crystals : Supercritical and subcritical bifurcations | |||||
言語 | en | |||||
著者 |
Uwaha, Makio
× Uwaha, Makio |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | This is the author's version of a work that was accepted for publication in Journal of Crystal Growth. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms, may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Crystal Growth. v.318, n.1, 2011, p.89–92, DOI:10.1016/j.jcrysgro.2010.10.078. | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | A1. Chirality conversion | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | A1. Growth models | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | A1. Computer simulation | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | A1. Stirring | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | A1. Recrystallization | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | A2. Growth form solutions | |||||
抄録 | ||||||
内容記述 | The chirality conversion of crystals by grinding in an open system under circulation is studied. A generalized classical nucleation model and simple reaction-type models both show that steady perfect chirality conversion is possible if circulation is weak. By increasing the circulation rate λ, the amplification rate of a chirality imbalance becomes small and the imbalance of chiral products in the steady state decreases with λ. The chiral steady state disappears above a critical strength of circulation. The transition between the racemic and the chiral state is continuous in the system of achiral molecules and discontinuous in the system of chiral molecules. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Elsevier | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1016/j.jcrysgro.2010.10.078 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 0022-0248 | |||||
書誌情報 |
en : Journal of Crystal Growth 巻 318, 号 1, p. 89-92, 発行日 2011-03 |
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著者版フラグ | ||||||
値 | author | |||||
URI | ||||||
識別子 | http://dx.doi.org/10.1016/j.jcrysgro.2010.10.078 | |||||
識別子タイプ | DOI | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/20566 | |||||
識別子タイプ | HDL |