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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Local atomic and electronic structures around Mg and Al dopants in LiNiO2 electrodes studied by XANES and ELNES and first-principles calculations

http://hdl.handle.net/2237/20781
8a4843f7-03fb-4c27-92b7-2692e67d782f
名前 / ファイル ライセンス アクション
PhysRevB_78_045108.pdf PhysRevB_78_045108.pdf (455.0 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2014-11-17
タイトル
タイトル Local atomic and electronic structures around Mg and Al dopants in LiNiO2 electrodes studied by XANES and ELNES and first-principles calculations
著者 Tatsumi, Kazuyoshi

× Tatsumi, Kazuyoshi

WEKO 54437

Tatsumi, Kazuyoshi

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Sasano, Yusuke

× Sasano, Yusuke

WEKO 54438

Sasano, Yusuke

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Muto, Shunsuke

× Muto, Shunsuke

WEKO 54439

Muto, Shunsuke

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Yoshida, Tomoko

× Yoshida, Tomoko

WEKO 54440

Yoshida, Tomoko

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Sasaki, Tsuyoshi

× Sasaki, Tsuyoshi

WEKO 54441

Sasaki, Tsuyoshi

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Horibuchi, Kayo

× Horibuchi, Kayo

WEKO 54442

Horibuchi, Kayo

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Takeuchi, Yoji

× Takeuchi, Yoji

WEKO 54443

Takeuchi, Yoji

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Ukyo, Yoshio

× Ukyo, Yoshio

WEKO 54444

Ukyo, Yoshio

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権利
権利情報 © 2008 The American Physical Society
抄録
内容記述 We investigated the local atomic and electronic structures around the dopants Mg and Al in a LiNiO2-based cathode material by the combination analysis of their K shell electron energy-loss near-edge structures, x-ray absorption near-edge structures, and first-principles calculations. The occupation sites of the dopants in initial and cycled samples were examined. On the basis of the atomic structures and chemical bonding states of the models whose theoretical spectra were most consistent with the experimental spectra, we discussed the effects of Al and Mg on Li diffusion and their roles in suppressing the degradation of battery properties.
内容記述タイプ Abstract
出版者
出版者 American Physical Society
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
ISSN
収録物識別子タイプ ISSN
収録物識別子 1098-0121
書誌情報 Physical Review B

巻 78, p. 045108-045108, 発行日 2008-07
著者版フラグ
値 publisher
URI
識別子 http://dx.doi.org/10.1103/PhysRevB.78.045108
識別子タイプ DOI
URI
識別子 http://hdl.handle.net/2237/20781
識別子タイプ HDL
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