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Capacity-Fading Mechanisms of LiNiO2-Based Lithium-Ion Batteries : II. Diagnostic Analysis by Electron Microscopy and Spectroscopy
http://hdl.handle.net/2237/20784
http://hdl.handle.net/2237/20784ece3e2d4-46fd-4b1e-8160-0d0101f32530
名前 / ファイル | ライセンス | アクション |
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J_Electrochem_Soc_2009-Muto-A371-7.pdf (1.6 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2014-11-17 | |||||
タイトル | ||||||
タイトル | Capacity-Fading Mechanisms of LiNiO2-Based Lithium-Ion Batteries : II. Diagnostic Analysis by Electron Microscopy and Spectroscopy | |||||
言語 | en | |||||
著者 |
Muto, Shunsuke
× Muto, Shunsuke× Sasano, Yusuke× Tatsumi, Kazuyoshi× Sasaki, Tsuyoshi× Horibuchi, Kayo× Takeuchi, Yoji× Ukyo, Yoshio |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | © The Electrochemical Society, Inc. 2009. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in Journal of The Electrochemical Society. v.156, n.5, 2009, p.A371-A377. | |||||
抄録 | ||||||
内容記述 | We used a suite of transmission electron microscopy (TEM) and associated electron spectroscopy methods to examine the local structure and changes in the electronic structure of Lini0.8Co0.15Al0.05O2 positive electrode material. We found a scattered rock-salt phase near grain surfaces and grain boundaries, where Ni^3+ turned to Ni^2+, deduced from relative intensity ratios and fine structures of the L2,3 white-line peaks of the transition metals. The spatial distribution of the degraded phase throughout the secondary particle was found using a scanning TEM-electron energy loss spectroscopy spectral imaging technique and multivariate analysis. The degradation process and its relationship to the surface reactions with electrolytes is discussed based on the spatial-distribution map of the degraded phases. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | The Electrochemical Society | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1149/1.3076137 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 0013-4651 | |||||
書誌情報 |
en : Journal of The Electrochemical Society 巻 156, 号 5, p. A371-A377, 発行日 2009-03 |
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著者版フラグ | ||||||
値 | publisher | |||||
URI | ||||||
識別子 | http://dx.doi.org/10.1149/1.3076137 | |||||
識別子タイプ | DOI | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/20784 | |||||
識別子タイプ | HDL |