{"_buckets": {"deposit": "cf41c043-4a78-44fb-a4f0-111eecd9775e"}, "_deposit": {"id": "18734", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "18734"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00018734"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2012-05", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "455", "bibliographicPageStart": "449", "bibliographicVolumeNumber": "205", "bibliographic_titles": [{"bibliographic_title": "Journal of Power Sources"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The performance of a LiNiO2-based cell has been shown to be significantly improved by Mg-doping of LiNi0.8Co0.15Al0.05O2 (Mg-doped NCA) cathode materials. In the present study, the effects of Mg-doping were examined by electrochemical impedance spectroscopy (EIS) and scanning transmission electron microscopy-electron energy loss spectroscopy. EIS analysis revealed that the activation energy of Mg-doped NCA for the charge-transfer reaction was larger than that of undoped NCA by a factor of \u223c10%; however, the charge-transfer resistance for Mg-doped NCA did not vary significantly with cycling, suggesting a different microstructure evolution compared to that of the undoped NCA. The spatial mapping of the product phases in the Mg-doped samples showed less degradation after charge\u2013discharge cycling tests at 70 \u00b0C compared to that in the undoped samples. In addition, degraded regions observed near the surface of the primary active material particles were identified as an intermediate structure, containing tetrahedrally coordinated Ni in contrast to the NiO-like phase found in the undoped samples. These microstructural observations are consistent with the electrochemical measurements.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://dx.doi.org/10.1016/j.jpowsour.2012.01.071"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/20830"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Elsevier"}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "This is the author\u0027s version of a work that was accepted for publication in Journal of Power Sources. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms, may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Power Sources. v.205, 2012, p.449\u2013455, DOI: 10.1016/j.jpowsour.2012.01.071"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0378-7753", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Muto, Shunsuke"}], "nameIdentifiers": [{"nameIdentifier": "54609", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tatsumi, Kazuyoshi"}], "nameIdentifiers": [{"nameIdentifier": "54610", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kojima, Yuji"}], "nameIdentifiers": [{"nameIdentifier": "54611", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Oka, Hideaki"}], "nameIdentifiers": [{"nameIdentifier": "54612", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kondo, Hiroki"}], "nameIdentifiers": [{"nameIdentifier": "54613", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Horibuchi, Kayo"}], "nameIdentifiers": [{"nameIdentifier": "54614", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ukyo, Yoshio"}], "nameIdentifiers": [{"nameIdentifier": "54615", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-02-21"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "JPS2012.pdf", "filesize": [{"value": "3.5 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 3500000.0, "url": {"label": "JPS2012.pdf", "url": "https://nagoya.repo.nii.ac.jp/record/18734/files/JPS2012.pdf"}, "version_id": "8f2bd976-6e4d-4df0-8411-fee63f1f1506"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Lithium ion secondary battery", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Electrochemical impedance spectroscopy", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Scanning transmission electron microscopy", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Electron energy loss spectroscopy", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Cathode", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Degradation", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Effect of Mg-doping on the degradation of LiNiO2-based cathode materials by combined spectroscopic methods", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Effect of Mg-doping on the degradation of LiNiO2-based cathode materials by combined spectroscopic methods"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/20830", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2014-11-19"}, "publish_date": "2014-11-19", "publish_status": "0", "recid": "18734", "relation": {}, "relation_version_is_last": true, "title": ["Effect of Mg-doping on the degradation of LiNiO2-based cathode materials by combined spectroscopic methods"], "weko_shared_id": null}