{"_buckets": {"deposit": "dfd619fb-6666-49f8-8a34-d2456be253e7"}, "_deposit": {"created_by": 17, "id": "2000042", "owner": "17", "owners": [17], "owners_ext": {"displayname": "図書情報係", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2000042"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02000042", "sets": ["322"]}, "author_link": [], "control_number": "2000042", "item_1615768549627": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "日付", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2021-10-07", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-10-07", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "37", "bibliographicPageEnd": "8724", "bibliographicPageStart": "8720", "bibliographicVolumeNumber": "16", "bibliographic_titles": [{"bibliographic_title": "Soft Matter", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "In this study, linear melt rheology of a single-tail tadpole-shaped polystyrene, ST-30/80, having ring and linear sizes of MR ∼ 30 kg mol^−1 and ML ∼ 80 kg mol^−1, respectively, was examined, and the effect of the ring size on rheological properties of tadpole polymers was discussed by comparing with the data of the previously reported tadpole samples having MR ∼ 60 kg mol^−1. ST-30/80 exhibits an entanglement plateau and shows a clearly slower terminal relaxation than that of its component ring and linear polymers. When the zero-shear viscosity η0 for ST-30/80 is plotted against the molecular weight of a linear tail chain, the data point lies on the single curve of η0 for 4- and 6-arm star polymers and the single-tail tadpoles with MR ∼ 60 kg mol^−1. These results suggest that the tadpole molecule in this study spontaneously forms a characteristic entanglement network, i.e., the intermolecular ring–linear threading, in the same manner as the previous tadpole samples, even though the size of the ring part is just slightly larger than the entanglement molecular weight (i.e., MR ∼ 1.8Me).", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Royal Society of Chemistry", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "関連情報", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1039/D0SM01098G", "subitem_relation_type_select": "DOI"}}]}, "item_9_source_id_7": {"attribute_name": "収録物識別子", "attribute_value_mlt": [{"subitem_source_identifier": "1744-683X", "subitem_source_identifier_type": "PISSN"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Doi, Yuya", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Takano, Atsushi", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Takahashi, Yoshiaki", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Matsushita, Yushu", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-10-07"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "20200731-Tadpole2-tiff.pdf", "filesize": [{"value": "568 KB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 568000.0, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2000042/files/20200731-Tadpole2-tiff.pdf"}, "version_id": "fcc90ced-bacd-4375-8ccd-5c6fc6fc1c07"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "tadpole-shaped polymer", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ring polymer", "subitem_subject_scheme": "Other"}, {"subitem_subject": "melt rheology", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ring-linear threading", "subitem_subject_scheme": "Other"}, {"subitem_subject": "retraction model", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Melt rheology of tadpole-shaped polystyrenes with different ring sizes", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Melt rheology of tadpole-shaped polystyrenes with different ring sizes", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["322"], "permalink_uri": "http://hdl.handle.net/2237/0002000042", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2021-05-18"}, "publish_date": "2021-05-18", "publish_status": "0", "recid": "2000042", "relation": {}, "relation_version_is_last": true, "title": ["Melt rheology of tadpole-shaped polystyrenes with different ring sizes"], "weko_shared_id": -1}
Melt rheology of tadpole-shaped polystyrenes with different ring sizes
http://hdl.handle.net/2237/0002000042
http://hdl.handle.net/2237/0002000042