{"_buckets": {"deposit": "7fef0acf-e12d-46e9-a907-23f42251ca0f"}, "_deposit": {"created_by": 17, "id": "2001523", "owner": "17", "owners": [17], "owners_ext": {"displayname": "\u56f3\u66f8\u60c5\u5831\u4fc2", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2001523"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02001523", "sets": []}, "author_link": [], "control_number": "2001523", "item_1615768549627": {"attribute_name": "\u51fa\u7248\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "\u65e5\u4ed8", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2022-02-09", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2021-02-09", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "3", "bibliographicPageEnd": "1374", "bibliographicPageStart": "1366", "bibliographicVolumeNumber": "54", "bibliographic_titles": [{"bibliographic_title": "Macromolecules", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "This study examined viscoeslastic properties of two flexible dumbbell-shaped polystyrene (PS) samples, D-30/120/30 and D-30/240/30, which possess the same ring size (MR \u223c 30 kg/mol) and different lengths of central linear chains (ML \u223c 120 and 240 kg/mol) in bulk and solution. In bulk, both dumbbell PS samples exhibited an extremely long entanglement plateau in dynamic oscillatory measurements, and their terminal relaxation behavior was not observed in our experimental window. In stress relaxation measurements, dumbbell samples in bulk exhibited considerably slower terminal relaxation than high-molecular-weight linear PS samples (M \u223c 10^6 g/mol), and a clear difference between two dumbbell PS samples was observed in the long time regime, i.e., terminal relaxation of D-30/240/30 is much slower than that of D-30/120/30. These results suggest that (i) the dumbbell polymer forms a characteristic \u201cnetwork\u201d where two rings on both ends in a molecule spontaneously thread the ring part of other dumbbell chains and (ii) this type of interchain interaction resulting in network formation becomes more dominant than usual entanglements similar to linear chains. The network of dumbbell chains starts to relax their stress when the intermolecular threading is released, and this release process tends to occur more frequently for the dumbbell with a shorter central chain, D-30/120/30, than that with a longer one, D-30/240/30. In dioctyl phthalate (DOP) solutions of D-30/240/30, where DOP is known as a \u03b8-solvent for PS at 22 \u00b0C, in a relatively high concentration regime (i.e., 20\u201330 wt %), the solutions exhibited an entanglement plateau and higher viscosity than the corresponding linear PS solutions, suggesting that the characteristic entanglement originating from intermolecular threading of dumbbell chains is still dominant in the solution. On the contrary, in a lower-concentration regime (\u22648 wt %), the D-30/240/30 solutions exhibited similar viscosities to the linear PS ones, wherein the dumbbell molecules behave like unentangled/isolated chains.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "\u95a2\u9023\u60c5\u5831", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acs.macromol.0c02050", "subitem_relation_type_select": "DOI"}}]}, "item_9_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Macromolecules], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-GZJFN8PTHJUUSBBRJSTK].\u201d", "subitem_rights_language": "en"}]}, "item_9_source_id_7": {"attribute_name": "\u53ce\u9332\u7269\u8b58\u5225\u5b50", "attribute_value_mlt": [{"subitem_source_identifier": "0024-9297", "subitem_source_identifier_type": "PISSN"}]}, "item_access_right": {"attribute_name": "\u30a2\u30af\u30bb\u30b9\u6a29", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Doi, Yuya", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Takano, Atsushi", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Takahashi, Yoshiaki", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Matsushita, Yushu", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2022-02-09"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "20210115-Dumbbell Rheology-tiff.pdf", "filesize": [{"value": "1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "mimetype": "application/pdf", "size": 1000000.0, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2001523/files/20210115-Dumbbell Rheology-tiff.pdf"}, "version_id": "fa86097a-eafe-4243-9267-8b423f713400"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Viscoelastic Properties of Dumbbell-Shaped Polystyrenes in Bulk and Solution", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Viscoelastic Properties of Dumbbell-Shaped Polystyrenes in Bulk and Solution", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/0002001523", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2021-10-15"}, "publish_date": "2021-10-15", "publish_status": "0", "recid": "2001523", "relation": {}, "relation_version_is_last": true, "title": ["Viscoelastic Properties of Dumbbell-Shaped Polystyrenes in Bulk and Solution"], "weko_shared_id": -1}