| Item type |
itemtype_ver1(1) |
| 公開日 |
2021-12-07 |
| タイトル |
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|
タイトル |
Synthesis and Properties of an 18π Aromatic Norcorrole P(V) Complex |
|
言語 |
en |
| 著者 |
Yoshida, Takuya
Shafie Siham Asyiqin
Kawashima, Hiroyuki
Fukui, Norihito
Shinokubo, Hiroshi
|
| アクセス権 |
|
|
アクセス権 |
open access |
|
アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利 |
|
|
言語 |
en |
|
権利情報 |
This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-KFUDNDUF6IXBHSVVGMJX].” |
| 内容記述 |
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|
内容記述タイプ |
Abstract |
|
内容記述 |
[16]Norcorrole is an antiaromatic ring-contracted porphyrinoid. Here, we show that the phosphorus insertion of the free-base [16]norcorrole switches its antiaromaticity to aromaticity. The treatment of a free-base meso-dimesityl[16]norcorrole with phosphorus tribromide in pyridine afforded an [18]norcorrole P(V) complex, which exhibited porphyrin-like absorption and fluorescence spectra. The phosphorus center adopted a distorted tetragonal pyramidal coordination geometry. The distinct aromatic nature of the [18]norcorrole P(V) complex was corroborated both experimentally and theoretically. |
|
言語 |
en |
| 出版者 |
|
|
出版者 |
ACS Publications |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 出版タイプ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 関連情報 |
|
|
関連タイプ |
isVersionOf |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
https://doi.org/10.1021/acs.orglett.1c00823 |
| 収録物識別子 |
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|
収録物識別子タイプ |
PISSN |
|
収録物識別子 |
1523-7060 |
| 書誌情報 |
en : Organic Letters
巻 23,
号 7,
p. 2826-2830,
発行日 2021-04-02
|
| ファイル公開日 |
|
|
日付 |
2022-04-02 |
|
日付タイプ |
Available |
P-norcorrole_revised.pdf (2 MB)
