{"_buckets": {"deposit": "5c0697ca-6a73-46a9-8c05-08acfe5c4cf4"}, "_deposit": {"created_by": 17, "id": "2001677", "owner": "17", "owners": [17], "owners_ext": {"displayname": "\u56f3\u66f8\u60c5\u5831\u4fc2", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2001677"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02001677", "sets": []}, "author_link": [], "control_number": "2001677", "item_1615768549627": {"attribute_name": "\u51fa\u7248\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "\u65e5\u4ed8", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2022-06-14", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2021-06-14", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "25", "bibliographicPageEnd": "14067", "bibliographicPageStart": "14060", "bibliographicVolumeNumber": "60", "bibliographic_titles": [{"bibliographic_title": "Angewandte Chemie International Edition", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "We report the synthesis and properties of acridino[2,1,9,8-klmna]acridine bisimide (AABI), a nitrogen-doped anthanthrene with two imide functionalities. AABI exhibits excellent electron affinity as evident by its low-lying LUMO level (\u22124.1\u2005eV vs. vacuum). Single-electron reduction of one AABI derivative afforded the corresponding radical anion, which was stable under ambient conditions. Photoconductivity measurements suggest that the intrinsic electron mobility of an N-phenethyl AABI derivative obeys a band-transport model. Accordingly, an electron mobility of 0.90\u2005cm^2\u2009V^\u22121\u2009s^\u22121 was attained with the corresponding single-crystal organic field-effect transistor (OFET) device. The vacuum-deposited OFET device consisting of a polycrystalline sample exhibited high electron mobility of up to 0.27\u2005cm^2\u2009V^\u22121\u2009s^\u22121 even in air. This study demonstrates that dual incorporation of both imide substituents and imine-type nitrogen atoms is an effective strategy to create novel electron-deficient \u03c0-systems.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "\u95a2\u9023\u60c5\u5831", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/anie.202102708", "subitem_relation_type_select": "DOI"}}]}, "item_9_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [K. Tajima, K. Matsuo, H. Yamada, S. Seki, N. Fukui, H. Shinokubo, Angew. Chem. Int. Ed. 2021, 60, 14060.], which has been published in final form at [https://doi.org/10.1002/anie.202102708]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley\u2019s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.\"", "subitem_rights_language": "en"}]}, "item_9_source_id_7": {"attribute_name": "\u53ce\u9332\u7269\u8b58\u5225\u5b50", "attribute_value_mlt": [{"subitem_source_identifier": "1433-7851", "subitem_source_identifier_type": "PISSN"}]}, "item_access_right": {"attribute_name": "\u30a2\u30af\u30bb\u30b9\u6a29", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Tajima, Keita", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Matsuo, Kyohei", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Yamada, Hiroko", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Seki, Shu", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Fukui, Norihito", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Shinokubo, Hiroshi", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2022-06-14"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Tajima-MS-rev-210413_hy.pdf", "filesize": [{"value": "8.3 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "mimetype": "application/pdf", "size": 8300000.000000001, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2001677/files/Tajima-MS-rev-210413_hy.pdf"}, "version_id": "8ff2942c-a822-41b5-a1d7-40706af0aa01"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Acridino[2,1,9,8-klmna]acridine Bisimides: An Electron-Deficient \u03c0-System for Robust Radical Anions and n-Type Organic Semiconductors", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Acridino[2,1,9,8-klmna]acridine Bisimides: An Electron-Deficient \u03c0-System for Robust Radical Anions and n-Type Organic Semiconductors", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/0002001677", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2021-12-07"}, "publish_date": "2021-12-07", "publish_status": "0", "recid": "2001677", "relation": {}, "relation_version_is_last": true, "title": ["Acridino[2,1,9,8-klmna]acridine Bisimides: An Electron-Deficient \u03c0-System for Robust Radical Anions and n-Type Organic Semiconductors"], "weko_shared_id": -1}