{"_buckets": {"deposit": "603288ac-a78e-428f-9165-2d6381d7225e"}, "_deposit": {"created_by": 17, "id": "2001915", "owner": "17", "owners": [17], "owners_ext": {"displayname": "図書情報係", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2001915"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02001915", "sets": ["1941"]}, "author_link": [], "control_number": "2001915", "item_1615768549627": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "日付", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2022-07-19", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2021-07-19", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "14", "bibliographicPageEnd": "10379", "bibliographicPageStart": "10371", "bibliographicVolumeNumber": "60", "bibliographic_titles": [{"bibliographic_title": "Inorganic Chemistry", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "We study a hexagonal oxide KLi6TaO6 (KLTO), proposed as a Li-ion solid electrolyte, by using a recently developed screening method. First-principles calculations predict that KLTO presents a good Li-ion conductivity (σLi) and a low activation energy (Ea). Li migration is enhanced by the presence of excess Li ions in the interstitial region via a kick-out mechanism. Our experimental results demonstrate that Sn-doped KLTO presents a conductivity of 1 × 10^–5 S cm^–1, a σLi of 6 × 10^–6 S cm^–1, and a relatively low Ea of 36 kJ mol^–1, which confirm the validity of the proposed screening method. Conversely, detailed analyses of the microstructure and X-ray diffraction patterns of KLTO samples indicate that a stable Li-excess condition is not achieved, therefore leaving potential improvement of the performance of KLTO as a Li-ion solid electrolyte by optimizing extrinsic doping and fabrication processes.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "関連情報", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acs.inorgchem.1c00902", "subitem_relation_type_select": "DOI"}}]}, "item_9_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Inorganic Chemistry], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-NNXFZJ6PBHZ2B8UEG3Z8].”", "subitem_rights_language": "en"}]}, "item_9_source_id_7": {"attribute_name": "収録物識別子", "attribute_value_mlt": [{"subitem_source_identifier": "0020-1669", "subitem_source_identifier_type": "PISSN"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Suzuki, Nobuaki", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Lee, Joohwi", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Masuoka, Yumi", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Ohta, Shingo", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Kobayashi, Tetsuro", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Asahi, Ryoji", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2022-07-19"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "KLTO_InorgChem_revised.pdf", "filesize": [{"value": "1.6 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "mimetype": "application/pdf", "size": 1600000.0, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2001915/files/KLTO_InorgChem_revised.pdf"}, "version_id": "21b6a677-cd92-4eeb-9c07-294d9d4bc80d"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Theoretical and Experimental Studies of KLi6TaO6 as a Li-Ion Solid Electrolyte", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Theoretical and Experimental Studies of KLi6TaO6 as a Li-Ion Solid Electrolyte", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["1941"], "permalink_uri": "http://hdl.handle.net/2237/0002001915", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2022-01-13"}, "publish_date": "2022-01-13", "publish_status": "0", "recid": "2001915", "relation": {}, "relation_version_is_last": true, "title": ["Theoretical and Experimental Studies of KLi6TaO6 as a Li-Ion Solid Electrolyte"], "weko_shared_id": -1}
Theoretical and Experimental Studies of KLi6TaO6 as a Li-Ion Solid Electrolyte
http://hdl.handle.net/2237/0002001915
http://hdl.handle.net/2237/0002001915