Item type |
itemtype_ver1(1) |
公開日 |
2022-01-14 |
タイトル |
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タイトル |
Synthesis of Benzo-Fused Cyclic Ketones via Metal-Free Ring Expansion of Cyclopropanols Enabled by Proton-Coupled Electron Transfer |
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言語 |
en |
著者 |
Kikuchi, Tomohiro
Yamada, Keiji
Yasui, Takeshi
Yamamoto, Yoshihiko
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アクセス権 |
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アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
権利 |
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言語 |
en |
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権利情報 |
This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-E9QPBBBHTKMB9QZ7HB7C].” |
内容記述 |
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内容記述 |
The metal-free ring expansion of cyclopropanols containing a pendant styrene moiety was successfully achieved using a proton-coupled electron transfer enabled by an organic photoredox catalyst. Through this, variants of 1-tetralone and 1-benzosuberone bearing a substituent at the benzylic position were selectively obtained through the regioselective ring closure of alkyl radical intermediates depending on the substitution pattern of the alkene moiety. |
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言語 |
en |
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内容記述タイプ |
Abstract |
出版者 |
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言語 |
en |
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出版者 |
ACS Publications |
言語 |
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言語 |
eng |
資源タイプ |
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資源タイプresource |
http://purl.org/coar/resource_type/c_6501 |
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タイプ |
journal article |
出版タイプ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
関連情報 |
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関連タイプ |
isVersionOf |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1021/acs.orglett.1c01436 |
収録物識別子 |
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収録物識別子タイプ |
PISSN |
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収録物識別子 |
1523-7060 |
書誌情報 |
en : Organic Letters
巻 23,
号 12,
p. 4710-4714,
発行日 2021-06-18
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ファイル公開日 |
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日付 |
2022-06-18 |
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日付タイプ |
Available |