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  1. D400 創薬科学研究科
  2. D400a 雑誌掲載論文
  3. 学術雑誌

Highly Enantioselective [2+2+2] Cycloaddition of Enediynes Enabled by Cobalt/Organophotoredox Cooperative Catalysis

http://hdl.handle.net/2237/0002002052
http://hdl.handle.net/2237/0002002052
0869ea19-0c50-43a8-8ff0-95525e89e92b
名前 / ファイル ライセンス アクション
ACS_Catal.pdf ACS_Catal.pdf (532 KB)
Item type itemtype_ver1(1)
公開日 2022-02-08
タイトル
タイトル Highly Enantioselective [2+2+2] Cycloaddition of Enediynes Enabled by Cobalt/Organophotoredox Cooperative Catalysis
言語 en
著者 Yasui, Takeshi

× Yasui, Takeshi

en Yasui, Takeshi

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Tatsumi, Rine

× Tatsumi, Rine

en Tatsumi, Rine

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Yamamoto, Yoshihiko

× Yamamoto, Yoshihiko

en Yamamoto, Yoshihiko

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Catalysis], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-IYC8D9M9XXDWVPMZNU2Z].”
キーワード
主題Scheme Other
主題 cobalt catalysis
キーワード
主題Scheme Other
主題 asymmetric catalysis
キーワード
主題Scheme Other
主題 metallaphotoredox
キーワード
主題Scheme Other
主題 cycloaddition
キーワード
主題Scheme Other
主題 enediynes
内容記述
内容記述 Herein, we report dual cobalt and photoredox catalysis enabled [2+2+2] cycloaddition of enediynes to produce tricyclic cyclohexadienes bearing a quaternary bridgehead carbon. A variety of enediynes were used, and the corresponding cyclohexadienes were obtained in good to high yields. The use of a chiral ligand, (S)-Segphos, enabled a highly enantioselective reaction allowing access to highly enantio-enriched cyclohexadienes.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 ACS Publications
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
関連情報
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1021/acscatal.1c02410
収録物識別子
収録物識別子タイプ EISSN
収録物識別子 2155-5435
書誌情報 en : ACS Catalysis

巻 11, 号 15, p. 9479-9484, 発行日 2021-08-06
ファイル公開日
日付 2022-08-06
日付タイプ Available
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