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Highly Enantioselective [2+2+2] Cycloaddition of Enediynes Enabled by Cobalt/Organophotoredox Cooperative Catalysis
http://hdl.handle.net/2237/0002002052
0869ea19-0c50-43a8-8ff0-95525e89e92b
名前 / ファイル | ライセンス | アクション | |
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Download is available from 2022/8/5.
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Item type | itemtype_ver1(1) | |||||||||||
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公開日 | 2022-02-08 | |||||||||||
タイトル | ||||||||||||
タイトル | Highly Enantioselective [2+2+2] Cycloaddition of Enediynes Enabled by Cobalt/Organophotoredox Cooperative Catalysis | |||||||||||
言語 | en | |||||||||||
著者 |
Yasui, Takeshi
× Yasui, Takeshi
× Tatsumi, Rine
× Yamamoto, Yoshihiko
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アクセス権 | ||||||||||||
アクセス権 | embargoed access | |||||||||||
アクセス権URI | http://purl.org/coar/access_right/c_f1cf | |||||||||||
権利 | ||||||||||||
言語 | en | |||||||||||
権利情報 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Catalysis], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-IYC8D9M9XXDWVPMZNU2Z].” | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | cobalt catalysis | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | asymmetric catalysis | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | metallaphotoredox | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | cycloaddition | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | enediynes | |||||||||||
内容記述 | ||||||||||||
内容記述 | Herein, we report dual cobalt and photoredox catalysis enabled [2+2+2] cycloaddition of enediynes to produce tricyclic cyclohexadienes bearing a quaternary bridgehead carbon. A variety of enediynes were used, and the corresponding cyclohexadienes were obtained in good to high yields. The use of a chiral ligand, (S)-Segphos, enabled a highly enantioselective reaction allowing access to highly enantio-enriched cyclohexadienes. | |||||||||||
言語 | en | |||||||||||
内容記述タイプ | Abstract | |||||||||||
出版者 | ||||||||||||
言語 | en | |||||||||||
出版者 | ACS Publications | |||||||||||
言語 | ||||||||||||
言語 | eng | |||||||||||
資源タイプ | ||||||||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||||||||
タイプ | journal article | |||||||||||
出版タイプ | ||||||||||||
出版タイプ | AM | |||||||||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||
関連情報 | ||||||||||||
関連タイプ | isVersionOf | |||||||||||
関連識別子 | ||||||||||||
識別子タイプ | DOI | |||||||||||
関連識別子 | https://doi.org/10.1021/acscatal.1c02410 | |||||||||||
収録物識別子 | ||||||||||||
収録物識別子タイプ | EISSN | |||||||||||
収録物識別子 | 2155-5435 | |||||||||||
書誌情報 |
en : ACS Catalysis 巻 11, 号 15, p. 9479-9484, 発行日 2021-08-06 |
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ファイル公開日 | ||||||||||||
日付 | 2022-08-06 | |||||||||||
日付タイプ | Available |