{"_buckets": {"deposit": "e46ec585-7fb0-449a-a60f-03fcfca45426"}, "_deposit": {"created_by": 17, "id": "2002066", "owner": "17", "owners": [17], "owners_ext": {"displayname": "\u56f3\u66f8\u60c5\u5831\u4fc2", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2002066"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02002066"}, "author_link": [], "item_1615768549627": {"attribute_name": "\u51fa\u7248\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "\u65e5\u4ed8", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2022-10-01", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2021-10", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "10", "bibliographicPageEnd": "2537", "bibliographicPageStart": "2534", "bibliographicVolumeNumber": "10", "bibliographic_titles": [{"bibliographic_title": "Asian Journal of Organic Chemistry", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "Radical cation [4+2] cycloaddition is an alternative strategy for constructing various six-membered rings that cannot be easily accessed by thermal [4+2] cycloaddition. Here, we developed an FeCl3/AgSbF6 co-initiator to promote radical cation [4+2] cycloaddition of non-conjugated tetrasubstituted alkenes with 2,3-dimethyl-1,3-butadiene. In the presence of 10\u2005mol% of FeCl3 and 30\u2005mol% of AgSbF6, the reaction proceeded smoothly in MeCN to provide the cycloadducts from tetrasubstituted alkenes having an electron-rich aromatic group, which improved the yield. We demonstrate the efficiency of an FeCl3/AgSbF6 co-initiator by comparing our finding to the results with previously reported iron(III) initiators in an investigation of the substrate scope. In addition, a kinetic study was conducted to elucidate the detailed reaction mechanism, in which the rate-determining step can be facilitated by intramolecular single electron transfer.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "\u95a2\u9023\u60c5\u5831", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/ajoc.202100473", "subitem_relation_type_select": "DOI"}}]}, "item_9_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [S. Ohmura, R. Isogai, K. Ishihara, Asian J. Org. Chem. 2021, 10, 2534.], which has been published in final form at [https://doi.org/10.1002/anie.202014946]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley\u2019s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.\"", "subitem_rights_language": "en"}]}, "item_9_source_id_7": {"attribute_name": "\u53ce\u9332\u7269\u8b58\u5225\u5b50", "attribute_value_mlt": [{"subitem_source_identifier": "2193-5815", "subitem_source_identifier_type": "EISSN"}]}, "item_access_right": {"attribute_name": "\u30a2\u30af\u30bb\u30b9\u6a29", "attribute_value_mlt": [{"subitem_access_right": "embargoed access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_f1cf"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ohmura, Shuhei", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Isogai, Ryosuke", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Ishihara, Kazuaki", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2022-10-01"}], "displaytype": "detail", "download_preview_message": "Download / Preview is available from 2022/9/30.", "file_order": 0, "filename": "Ohmura_S_Isogai_R_Ishihara_K.pdf", "filesize": [{"value": "485 KB"}], "format": "application/pdf", "future_date_message": "Download is available from 2022/9/30.", "is_thumbnail": false, "mimetype": "application/pdf", "size": 485000.0, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2002066/files/Ohmura_S_Isogai_R_Ishihara_K.pdf"}, "version_id": "470d41e3-5375-4668-b91a-40250149f1ca"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Radical Cation [4+2] Cycloaddition of Non-Conjugated Tetrasubstituted Alkenes by an FeCl3/AgSbF6 Co-Initiator", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Radical Cation [4+2] Cycloaddition of Non-Conjugated Tetrasubstituted Alkenes by an FeCl3/AgSbF6 Co-Initiator", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/0002002066", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2022-02-10"}, "publish_date": "2022-02-10", "publish_status": "0", "recid": "2002066", "relation": {}, "relation_version_is_last": true, "title": ["Radical Cation [4+2] Cycloaddition of Non-Conjugated Tetrasubstituted Alkenes by an FeCl3/AgSbF6 Co-Initiator"], "weko_shared_id": -1}