| Item type |
itemtype_ver1(1) |
| 公開日 |
2022-05-09 |
| タイトル |
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|
タイトル |
Acridinium salts as photoredox organocatalysts for photomediated cationic RAFT and DT polymerizations of vinyl ethers |
|
言語 |
en |
| 著者 |
Matsuda, Marina
Uchiyama, Mineto
Itabashi, Yuki
Ohkubo, Kei
Kamigaito, Masami
|
| アクセス権 |
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|
アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 内容記述 |
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|
内容記述タイプ |
Abstract |
|
内容記述 |
A series of acridinium salts with high excited-state oxidative power are employed as photoredox organocatalysts in conjunction with various thioesters, such as trithiocarbonate, dithiocarbamate, and xanthate, and thioacetals for photomediated cationic reversible addition–fragmentation chain-transfer (RAFT) and degenerative chain-transfer (DT) polymerizations of vinyl ethers under visible light. A combination of acridinium salts and trithiocarbonate or thioacetal induces relatively fast and controlled cationic polymerization of various alkyl vinyl ethers under blue, green, and white LEDs, where the photoexcited acridinium salts generate cationic species from the sulfur compounds via the mesolytic cleavage of carbon–sulfur bonds through the formation of radical cations. An acridinium salt with a higher excited-state oxidative power induces faster cationic polymerization. Temporal control of the polymerization is achievable by switching the light on and off, although the polymerization in the dark is not completely halted. The controlled nature of the polymerization further enables the synthesis of block copolymers of alkyl vinyl ethers via sequential monomer addition. |
|
言語 |
en |
| 出版者 |
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|
出版者 |
Royal Society of Chemistry |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
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|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 出版タイプ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 関連情報 |
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|
関連タイプ |
isVersionOf |
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|
識別子タイプ |
DOI |
|
|
関連識別子 |
https://doi.org/10.1039/D1PY01568K |
| 収録物識別子 |
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|
収録物識別子タイプ |
PISSN |
|
収録物識別子 |
1759-9954 |
| 書誌情報 |
en : Polymer Chemistry
巻 13,
号 8,
p. 1031-1039,
発行日 2022-02-28
|
| ファイル公開日 |
|
|
日付 |
2023-02-28 |
|
日付タイプ |
Available |
POLYMER_CHEMISTRY_13_8_2022_1031-1039.pdf (1.9 MB)
