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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Indeno[1,2,3,4-pqra]Perylene : A Medium-Sized Aromatic Hydrocarbon Exhibiting Full-Range Visible-Light Absorption

http://hdl.handle.net/2237/0002002693
http://hdl.handle.net/2237/0002002693
505b1838-58dd-4d35-b938-3bd1b1594511
名前 / ファイル ライセンス アクション
indenoperylene_MS_rev3.pdf indenoperylene_MS_rev3.pdf (2.1 MB)
Item type itemtype_ver1(1)
公開日 2022-05-10
タイトル
タイトル Indeno[1,2,3,4-pqra]Perylene : A Medium-Sized Aromatic Hydrocarbon Exhibiting Full-Range Visible-Light Absorption
言語 en
著者 Kato, Masaki

× Kato, Masaki

en Kato, Masaki

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Fukui, Norihito

× Fukui, Norihito

en Fukui, Norihito

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Shinokubo, Hiroshi

× Shinokubo, Hiroshi

en Shinokubo, Hiroshi

Search repository
アクセス権
アクセス権 embargoed access
アクセス権URI http://purl.org/coar/access_right/c_f1cf
権利
言語 en
権利情報 "This is the peer reviewed version of the following article: [M. Kato, N. Fukui, H. Shinokubo, Chem. Eur. J. 2022, 28, e202103647.], which has been published in final form at [https://doi.org/10.1002/chem.202103647]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited."
内容記述
内容記述 We report the synthesis and properties of indeno[1,2,3,4-pqra]perylene, which was prepared by the fusion of one anthracene unit with one naphthalene unit via three carbon-carbon bonds. The synthetic route through two-fold C−H arylation enabled not only the synthesis of unsubstituted indenoperylene, but also rapid access to its arylated derivatives on the gram scale. Indenoperylene is a medium-sized aromatic hydrocarbon with the composition C24H12 that is isomeric to coronene. Nevertheless, its absorption covers the entire visible region owing to its small HOMO-LUMO gap. Furthermore, indenoperylene exhibits high stability despite the absence of peripheral substituents. We propose that the unique electronic structure of indenoperylene originates from the coexistence of an electron-withdrawing subunit (benzoaceanthrylene) and an electron-donating subunit (perylene). The electronic properties of indenoperylene were modulated via post-functionalization through regioselective bromination. The current research demonstrates that indenoperylene is a promising candidate as a main skeleton for near-infrared-responsive and redox-active materials.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
関連情報
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/chem.202103647
収録物識別子
収録物識別子タイプ EISSN
収録物識別子 1521-3765
書誌情報 en : Chemistry - A European Journal

巻 28, 号 2, p. e202103647, 発行日 2022-01-10
ファイル公開日
日付 2023-01-10
日付タイプ Available
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