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  1. A500 情報学部/情報学研究科・情報文化学部・情報科学研究科
  2. A500a 雑誌掲載論文
  3. 学術雑誌

Synthesis and characterization of methoxybenzene-linked polyimides formed by 1,4-addition to bismaleimides

http://hdl.handle.net/2237/0002003809
http://hdl.handle.net/2237/0002003809
1004692d-bf48-451e-82e1-e025b1049270
名前 / ファイル ライセンス アクション
Polymer2022v238A124326_RevisedMN_ToCL.pdf Polymer2022v238A124326_RevisedMN_ToCL.pdf (1.2 MB)
 Download is available from 2024/1/2.
Item type itemtype_ver1(1)
公開日 2022-09-26
タイトル
タイトル Synthesis and characterization of methoxybenzene-linked polyimides formed by 1,4-addition to bismaleimides
言語 en
著者 Hor, Seanghai

× Hor, Seanghai

en Hor, Seanghai

Search repository
Oyama, Kin-ichi

× Oyama, Kin-ichi

en Oyama, Kin-ichi

Search repository
Koga, Nobuaki

× Koga, Nobuaki

en Koga, Nobuaki

Search repository
Tsukamoto, Masaki

× Tsukamoto, Masaki

en Tsukamoto, Masaki

Search repository
アクセス権
アクセス権 embargoed access
アクセス権URI http://purl.org/coar/access_right/c_f1cf
権利
言語 en
権利情報 © 2022. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
内容記述
内容記述 Methoxybenzene-linked polyimides were synthesized by a trifluoromethanesulfonic acid (TfOH)-catalyzed 1,4-addition (Michael addition) reaction. Newly synthesized 1,3-bis(3,5-dimethoxyphenoxy)propane and known 5,5′-oxybis(1,3-dimethoxybenzene) as nucleophilic monomers were reacted with several bismaleimides in the presence of a catalytic amount of TfOH in m-cresol. Use of 1,3-bis(3,5-dimethoxyphenoxy)propane afforded polyimides with number average molecular weights (Mn)s of 8000–15000. However, polyimides with Mn of 4000 or less were obtained when 5,5′-oxybis(1,3-dimethoxybenzene) was employed as a monomer. The synthesized polyimides showed good thermostability as judged by 10% weight loss temperatures between 417 and 441 °C. Their glass transition temperatures were around 200 °C. These polymers featured a wide range of solubility in organic solvents such as m-cresol, DMF, pyridine, and chloroform.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 Elsevier
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
関連情報
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1016/j.polymer.2021.124326
収録物識別子
収録物識別子タイプ PISSN
収録物識別子 0032-3861
書誌情報 en : Polymer

巻 238, p. 124326, 発行日 2023-01-03
ファイル公開日
日付 2024-01-03
日付タイプ Available
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