| Item type |
itemtype_ver1(1) |
| 公開日 |
2022-11-30 |
| タイトル |
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|
タイトル |
Multiselective Diels–Alder Reaction of α-Arylacroleins Catalyzed by Boron Tribromide-Assisted Chiral Phosphoric Acids |
|
言語 |
en |
| 著者 |
Matsui, Kai
Toh, Kohei
Hatano, Manabu
Ishihara, Kazuaki
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| アクセス権 |
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|
アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 権利 |
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|
言語 |
en |
|
権利情報 |
This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-YTEVYMVA9ZYDS5FKGP4Z].” |
| 内容記述 |
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|
内容記述タイプ |
Abstract |
|
内容記述 |
A multiselective Diels–Alder (DA) reaction of α-arylacroleins with cyclopentadiene using BBr3-assisted chiral BINOL-derived phosphoric acid catalysts has been developed. This unusual exo- and enantioselective DA reaction can be multicontrolled by the chiral cavity of the in situ-formed acid–base cooperative catalysts, in particular, suppressing the competitive hetero Diels–Alder (HDA) reaction effectively. |
|
言語 |
en |
| 出版者 |
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出版者 |
ACS Publications |
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言語 |
en |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 出版タイプ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 関連情報 |
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|
関連タイプ |
isVersionOf |
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|
識別子タイプ |
DOI |
|
|
関連識別子 |
https://doi.org/10.1021/acs.orglett.2c02747 |
| 収録物識別子 |
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|
収録物識別子タイプ |
PISSN |
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収録物識別子 |
1523-7060 |
| 書誌情報 |
en : Organic Letters
巻 24,
号 35,
p. 6483-6488,
発行日 2022-09-09
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| ファイル公開日 |
|
|
日付 |
2023-09-09 |
|
日付タイプ |
Available |
Manuscript.pdf (1.3 MB)
