{"_buckets": {"deposit": "c2edc79b-9ff0-450f-a7a8-be04bc428fcb"}, "_deposit": {"created_by": 17, "id": "2004254", "owner": "17", "owners": [17], "owners_ext": {"displayname": "repository", "username": "repository"}, "pid": {"revision_id": 0, "type": "depid", "value": "2004254"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:02004254", "sets": ["322"]}, "author_link": [], "item_1615768549627": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_1629683748249": {"attribute_name": "日付", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2023-05-23", "subitem_date_issued_type": "Available"}]}, "item_9_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2022-05-23", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "5", "bibliographicPageEnd": "5821", "bibliographicPageStart": "5811", "bibliographicVolumeNumber": "5", "bibliographic_titles": [{"bibliographic_title": "ACS Applied Energy Materials", "bibliographic_titleLang": "en"}]}]}, "item_9_description_4": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "In this study, we developed Cu(CrxMn1–x)2O4/CuCrxMn1–xO2 (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9, 1.0) redox couples for medium-high temperature (500–1000 °C) redox-type thermochemical energy storage systems. Structural characterization, redox behavior, reoxidation behavior and kinetic analysis, heat storage capacity, and cyclability were investigated using SEM-EDS, XRD, TGA, and DSC, respectively. When x = 0–0.5, samples exhibited decreasing operating temperatures with increasing amounts of Cr, whereas they lost their reversibility when x \u003e 0.5. R-CuCr0.1Mn0.9 and R-CuCr0.3Mn0.7 showed a faster reaction rate than R-CuMn because samples with small amounts of Cr required a lower activation energy (Ea) for reoxidation. The DSC results showed that a small amount of Cr improved the heat storage capacity of materials. In the cyclability test, the introduction of a small amount of Cr did not cause the deterioration of cyclic properties.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_9_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_9_relation_43": {"attribute_name": "関連情報", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acsaem.2c00178", "subitem_relation_type_select": "DOI"}}]}, "item_9_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Applied Energy Materials], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-4M6PSXNMK5HTCHYFIXHW].”", "subitem_rights_language": "en"}]}, "item_9_source_id_7": {"attribute_name": "収録物識別子", "attribute_value_mlt": [{"subitem_source_identifier": "2574-0962", "subitem_source_identifier_type": "PISSN"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "embargoed access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_f1cf"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Chen, Xiaoyu", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Kubota, Mitsuhiro", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Kobayashi, Noriyuki", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Yamashita, Seiji", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Kita, Hideki", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2023-05-23"}], "displaytype": "detail", "download_preview_message": "Download / Preview is available from 2023/5/22.", "file_order": 0, "filename": "ACS_AppliedEnergyMaterials-Kubota.pdf", "filesize": [{"value": "5.1 MB"}], "format": "application/pdf", "future_date_message": "Download is available from 2023/5/22.", "is_thumbnail": false, "mimetype": "application/pdf", "size": 5100000.0, "url": {"objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/2004254/files/ACS_AppliedEnergyMaterials-Kubota.pdf"}, "version_id": "54802223-bfbe-4017-a742-b40464ddd8c3"}, {"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2023-05-23"}], "displaytype": "detail", "download_preview_message": "Download / Preview is available from 2023/5/22.", "file_order": 1, "filename": "ACS_AppliedEnergyMaterials-Supplementary-Kubota.pdf", "filesize": [{"value": "4.9 MB"}], "format": "application/pdf", "future_date_message": "Download is available from 2023/5/22.", "is_thumbnail": false, "mimetype": "application/pdf", "size": 4900000.0, "url": {"objectType": "dataset", "url": "https://nagoya.repo.nii.ac.jp/record/2004254/files/ACS_AppliedEnergyMaterials-Supplementary-Kubota.pdf"}, "version_id": "ead9e4d2-b45d-481d-a75a-0f7f04d46890"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Effect of Cr Addition on Cu–Mn Spinel/Delafossite Redox Couples for Medium-High Temperature Thermochemical Energy Storage", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Effect of Cr Addition on Cu–Mn Spinel/Delafossite Redox Couples for Medium-High Temperature Thermochemical Energy Storage", "subitem_title_language": "en"}]}, "item_type_id": "40001", "owner": "17", "path": ["322"], "permalink_uri": "http://hdl.handle.net/2237/0002004254", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2022-12-02"}, "publish_date": "2022-12-02", "publish_status": "0", "recid": "2004254", "relation": {}, "relation_version_is_last": true, "title": ["Effect of Cr Addition on Cu–Mn Spinel/Delafossite Redox Couples for Medium-High Temperature Thermochemical Energy Storage"], "weko_shared_id": -1}