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Chemoselective Conversion from α-Hydroxy Acids to α-Keto Acids Enabled by Nitroxyl-Radical-Catalyzed Aerobic Oxidation
http://hdl.handle.net/2237/25002
http://hdl.handle.net/2237/250022c403a7c-09fb-4176-b1f0-b4757aa0c641
名前 / ファイル | ライセンス | アクション |
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acs_orglett_6b01964.pdf (783.2 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2016-11-07 | |||||
タイトル | ||||||
タイトル | Chemoselective Conversion from α-Hydroxy Acids to α-Keto Acids Enabled by Nitroxyl-Radical-Catalyzed Aerobic Oxidation | |||||
言語 | en | |||||
著者 |
Furukawa, Keisuke
× Furukawa, Keisuke× Inada, Haruki× Shibuya, Masatoshi× Yamamoto, Yoshihiko |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | This is an open access article published under an ACS AuthorChoice License, which permits<br/>copying and redistribution of the article or any adaptations for non-commercial purposes. | |||||
抄録 | ||||||
内容記述 | The chemoselective oxidation of α-hydroxy acids to α-keto acids catalyzed by 2-azaadamantane N-oxyl (AZADO), a nitroxyl radical catalyst, is described. Although α-keto acids are labile and can easily release CO2 under oxidation conditions, the use of molecular oxygen as a cooxidant enables the desired chemoselective oxidation. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | ACS Publications | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1021/acs.orglett.6b01964 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1523-7060 | |||||
書誌情報 |
en : ORGANIC LETTERS 巻 18, 号 17, p. 4230-4233, 発行日 2016-08 |
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著者版フラグ | ||||||
値 | publisher | |||||
URI | ||||||
識別子 | http://doi.org/10.1021/acs.orglett.6b01964 | |||||
識別子タイプ | DOI | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/25002 | |||||
識別子タイプ | HDL |