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Asymmetric Double Tetragonal Domain Packing from ABC Triblock Terpolymer Blends with Chain Length Difference
http://hdl.handle.net/2237/25215
http://hdl.handle.net/2237/25215d601e423-7baf-4281-9897-4560d9602b45
| 名前 / ファイル | ライセンス | アクション |
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Supporting_Information.pdf ファイル公開：2017/09/08 (583.7 kB)
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Manuscript.pdf ファイル公開：2017/09/08 (931.9 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2016-12-16 | |||||
| タイトル | ||||||
| タイトル | Asymmetric Double Tetragonal Domain Packing from ABC Triblock Terpolymer Blends with Chain Length Difference | |||||
| 言語 | en | |||||
| 著者 |
Asai, Yusuke
× Asai, Yusuke× Takano, Atsushi× Matsushita, Yushu |
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| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 権利 | ||||||
| 言語 | en | |||||
| 権利情報 | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Macromolecules], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubsdc3.acs.org/articlesonrequest/AOR-bCui3cBncBNP8h9ujIeU].” | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | A specific phase structure was observed for binary blends of poly(isoprene)-block-poly(styrene)-block-poly(2-vinylpyridine) (ISP) triblock terpolymers with asymmetric chain lengths of two end-blocks. Tetragonal-packed cylinders were obtained from various binary blends on a wide range of volume fractions, although the sizes of I and P cylinders were highly asymmetric. Those structures have never been found for monodisperse ABC triblock terpolymers, and the three specific features have been confirmed: (1) I cylinders were metamorphosed into rod domains, and their interfaces have nonconstant mean curvatures; (2) the cross-sectional area ratio of I/P domain is qualitatively changed with the volume fraction of each component; and (3) spherical and cylindrical domains of P component coexist. The molecular design adopted in the present work, that is, I and P blocks in two parent terpolymers have both fairly large chain length difference, must lead to these new morphologies. | |||||
| 言語 | en | |||||
| 出版者 | ||||||
| 出版者 | ACS Publications | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | journal article | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1021/acs.macromol.6b01670 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 0024-9297 | |||||
| 書誌情報 |
en : Macromolecules 巻 49, 号 18, p. 6940-6946, 発行日 2016-09-08 |
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| 著者版フラグ | ||||||
| 値 | author | |||||
| URI | ||||||
| 識別子 | http://doi.org/10.1021/acs.macromol.6b01670 | |||||
| 識別子タイプ | DOI | |||||
| URI | ||||||
| 識別子 | http://hdl.handle.net/2237/25215 | |||||
| 識別子タイプ | HDL | |||||
