{"_buckets": {"deposit": "3257812c-79a5-4f33-a446-341ff55dbea6"}, "_deposit": {"id": "24069", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "24069"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00024069"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2016-10-03", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "40", "bibliographicPageEnd": "27161", "bibliographicPageStart": "27151", "bibliographicVolumeNumber": "8", "bibliographic_titles": [{"bibliographic_title": "ACS Applied Materials \u0026 Interfaces"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Independently controlling the shape anisotropy and chemical composition of multinary semiconductor particles is important for preparing highly efficient photocatalysts. In this study, we prepared ZnS\u2013AgInS2 solid solution ((AgIn)xZn2(1\u2013x)S2, ZAIS) nanoparticles with well-controlled anisotropic shapes, rod and rice shapes, by reacting corresponding metal acetates with a mixture of sulfur compounds with different reactivities, elemental sulfur, and 1,3-dibutylthiourea, via a two-step heating-up process. The chemical composition predominantly determined the energy gap of ZAIS particles: the fraction of Zn2+ in rod-shaped particles was tuned by the ratio of metal precursors used in the nanocrystal formation, while postpreparative Zn2+ doping was necessary to increase the Zn2+ fraction in the rice-shaped particles. The photocatalytic H2 evolution rate with irradiation to ZAIS particles dispersed in an aqueous solution was significantly dependent on the chemical composition in the case of using photocatalyst particles with a constant morphology. In contrast, photocatalytic activity at the optimum ZAIS composition, x of 0.35\u20130.45, increased with particle morphology in the order of rice (size: ca. 9 \u00d7 ca. 16 nm) \u003c sphere (diameter: ca. 5.5 nm) \u003c rod (size: 4.6 \u00d7 27 nm). The highest apparent quantum yield for photocatalytic H2 evolution was 5.9% for rod-shaped ZAIS particles, being about two times larger than that obtained with spherical particles.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://doi.org/10.1021/acsami.6b10408"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/26273"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications"}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u201cThis document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Applied Materials \u0026 Interfaces], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-Z8uXhEMXmyBwkX5VhAik].\u201d"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1944-8244", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Torimoto, Tsukasa"}], "nameIdentifiers": [{"nameIdentifier": "71441", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kamiya, Yutaro"}], "nameIdentifiers": [{"nameIdentifier": "71442", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kameyama, Tatsuya"}], "nameIdentifiers": [{"nameIdentifier": "71443", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishi, Hiroyasu"}], "nameIdentifiers": [{"nameIdentifier": "71444", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Uematsu, Taro"}], "nameIdentifiers": [{"nameIdentifier": "71445", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kuwabata, Susumu"}], "nameIdentifiers": [{"nameIdentifier": "71446", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shibayama, Tamaki"}], "nameIdentifiers": [{"nameIdentifier": "71447", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-10-03"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "am-2016-10408pR1.pdf", "filesize": [{"value": "1.9 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1900000.0, "url": {"label": "am-2016-10408pR1.pdf \u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2017/10/03", "url": "https://nagoya.repo.nii.ac.jp/record/24069/files/am-2016-10408pR1.pdf"}, "version_id": "0bb24d10-8c11-4ba6-b728-73e4ec86436a"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Controlling Shape Anisotropy of ZnS\u2013AgInS2 Solid Solution Nanoparticles for Improving Photocatalytic Activity", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Controlling Shape Anisotropy of ZnS\u2013AgInS2 Solid Solution Nanoparticles for Improving Photocatalytic Activity"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/26273", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2017-05-10"}, "publish_date": "2017-05-10", "publish_status": "0", "recid": "24069", "relation": {}, "relation_version_is_last": true, "title": ["Controlling Shape Anisotropy of ZnS\u2013AgInS2 Solid Solution Nanoparticles for Improving Photocatalytic Activity"], "weko_shared_id": null}