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Synthesis of bright red-emissive dicyanoetheno-bridged hexa-peri-hexabenzocoronene dimers
http://hdl.handle.net/2237/26573
http://hdl.handle.net/2237/265732e4d739e-4313-4d52-a03d-d9f6a0adf818
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
Oda170110OBC-revised.pdf ファイル公開：2018/02/14 (2.8 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2017-06-06 | |||||
| タイトル | ||||||
| タイトル | Synthesis of bright red-emissive dicyanoetheno-bridged hexa-peri-hexabenzocoronene dimers | |||||
| 言語 | en | |||||
| 著者 |
Oda, Kazuma
× Oda, Kazuma× Hiroto, Satoru× Hisaki, Ichiro× Shinokubo, Hiroshi |
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| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The introduction of a dicyanomethyl anion group to hexa-peri-hexabenzocoronene (HBC) substantially enhanced the emission properties of HBC due to a large perturbation of its electronic structure. In addition, dicyanoetheno-bridged HBC dimers obtained from oxidation of a dicyanomethyl HBC anion exhibited bright red emission in solution and solid states. Intramolecular charge transfer interactions between the HBC units and the dicyanoethene bridge induced solvatochromic behaviour in their emission spectra. Dicyanoetheno-bridged HBC dimers exhibited cis–trans photoisomerization behaviour in the solution, affording the mixture in cis-isomer dominance in the photostationary state. Theoretical calculations revealed that the cis-isomer is more thermodynamically stable than the trans-isomer. | |||||
| 言語 | en | |||||
| 出版者 | ||||||
| 出版者 | Royal Society of Chemistry | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | journal article | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1039/C6OB02775J | |||||
| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 1477-0520 | |||||
| 書誌情報 |
en : Organic & Biomolecular Chemistry 巻 15, 号 6, p. 1426-1434, 発行日 2017-02-14 |
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| 著者版フラグ | ||||||
| 値 | author | |||||
| URI | ||||||
| 識別子 | http://doi.org/10.1039/C6OB02775J | |||||
| 識別子タイプ | DOI | |||||
| URI | ||||||
| 識別子 | http://hdl.handle.net/2237/26573 | |||||
| 識別子タイプ | HDL | |||||
