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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Synthesis of bright red-emissive dicyanoetheno-bridged hexa-peri-hexabenzocoronene dimers

http://hdl.handle.net/2237/26573
2e4d739e-4313-4d52-a03d-d9f6a0adf818
名前 / ファイル ライセンス アクション
Oda170110OBC-revised.pdf Oda170110OBC-revised.pdf ファイル公開:2018/02/14 (2.8 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2017-06-06
タイトル
タイトル Synthesis of bright red-emissive dicyanoetheno-bridged hexa-peri-hexabenzocoronene dimers
著者 Oda, Kazuma

× Oda, Kazuma

WEKO 72161

Oda, Kazuma

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Hiroto, Satoru

× Hiroto, Satoru

WEKO 72162

Hiroto, Satoru

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Hisaki, Ichiro

× Hisaki, Ichiro

WEKO 72163

Hisaki, Ichiro

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Shinokubo, Hiroshi

× Shinokubo, Hiroshi

WEKO 72164

Shinokubo, Hiroshi

Search repository
抄録
内容記述 The introduction of a dicyanomethyl anion group to hexa-peri-hexabenzocoronene (HBC) substantially enhanced the emission properties of HBC due to a large perturbation of its electronic structure. In addition, dicyanoetheno-bridged HBC dimers obtained from oxidation of a dicyanomethyl HBC anion exhibited bright red emission in solution and solid states. Intramolecular charge transfer interactions between the HBC units and the dicyanoethene bridge induced solvatochromic behaviour in their emission spectra. Dicyanoetheno-bridged HBC dimers exhibited cis–trans photoisomerization behaviour in the solution, affording the mixture in cis-isomer dominance in the photostationary state. Theoretical calculations revealed that the cis-isomer is more thermodynamically stable than the trans-isomer.
内容記述タイプ Abstract
出版者
出版者 Royal Society of Chemistry
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
ISSN
収録物識別子タイプ ISSN
収録物識別子 1477-0520
書誌情報 Organic & Biomolecular Chemistry

巻 15, 号 6, p. 1426-1434, 発行日 2017-02-14
著者版フラグ
値 author
URI
識別子 http://doi.org/10.1039/C6OB02775J
識別子タイプ DOI
URI
識別子 http://hdl.handle.net/2237/26573
識別子タイプ HDL
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