{"_buckets": {"deposit": "adc18511-7883-455e-b905-25e07bdb8ad5"}, "_deposit": {"id": "24552", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "24552"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00024552", "sets": ["1905"]}, "author_link": ["72669", "72670", "72671", "72672"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2017-04-07", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "4", "bibliographicPageEnd": "2852", "bibliographicPageStart": "2848", "bibliographicVolumeNumber": "7", "bibliographic_titles": [{"bibliographic_title": "ACS Catalysis", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The Brønsted acid-catalyzed intramolecular hydroalkoxylation and hydroamination of unactivated alkynes are described. We found that unactivated alkynes are electrophilically activated by a catalytic amount of bis(trifluoromethanesulfonyl)imide to undergo intramolecular hydroalkoxylation and hydroamination. In the presence of silane, the formed reactive exo-cyclic enol ether and exo-cyclic enamine intermediates are effectively reduced to the corresponding saturated cyclic ethers and N-protected cyclic amines. The 2,4-cis and 2,5-cis pyrrolidine derivatives are produced with high diastereoselectivity. Taking advantage of this selectivity, the 2,5-cis-disubstituted prolinol was also synthesized from glutamic acid in the optically active form.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/26769"}, {"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://dx.doi.org/10.1021/acscatal.7b00403"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acscatal.7b00403", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Catalysis], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-ccnW7GCz94tz5qnyYxff].”", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "2155-5435", "subitem_source_identifier_type": "EISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Shibuya, Masatoshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "72669", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fujita, Shoji", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "72670", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Abe, Masanori", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "72671", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamamoto, Yoshihiko", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "72672", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-04-07"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "ACS_catalysis_shibuya_rev2.pdf", "filesize": [{"value": "991.3 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 991300.0, "url": {"label": "ACS_catalysis_shibuya_rev2.pdf ファイル公開：2018/04/07", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/24552/files/ACS_catalysis_shibuya_rev2.pdf"}, "version_id": "630bb5d9-3480-492d-bd92-c2417f0cdc32"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "alkyne", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Brønsted acid", "subitem_subject_scheme": "Other"}, {"subitem_subject": "electrophilic activation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "hydroalkoxylation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "hydroamination", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Brønsted Acid/Silane Catalytic System for Intramolecular Hydroalkoxylation and Hydroamination of Unactivated Alkynes", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Brønsted Acid/Silane Catalytic System for Intramolecular Hydroalkoxylation and Hydroamination of Unactivated Alkynes", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["1905"], "permalink_uri": "http://hdl.handle.net/2237/26769", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2017-07-05"}, "publish_date": "2017-07-05", "publish_status": "0", "recid": "24552", "relation": {}, "relation_version_is_last": true, "title": ["Brønsted Acid/Silane Catalytic System for Intramolecular Hydroalkoxylation and Hydroamination of Unactivated Alkynes"], "weko_shared_id": -1}