{"_buckets": {"deposit": "adc18511-7883-455e-b905-25e07bdb8ad5"}, "_deposit": {"id": "24552", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "24552"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00024552"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2017-04-07", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "4", "bibliographicPageEnd": "2852", "bibliographicPageStart": "2848", "bibliographicVolumeNumber": "7", "bibliographic_titles": [{"bibliographic_title": "ACS Catalysis"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The Br\u00f8nsted acid-catalyzed intramolecular hydroalkoxylation and hydroamination of unactivated alkynes are described. We found that unactivated alkynes are electrophilically activated by a catalytic amount of bis(trifluoromethanesulfonyl)imide to undergo intramolecular hydroalkoxylation and hydroamination. In the presence of silane, the formed reactive exo-cyclic enol ether and exo-cyclic enamine intermediates are effectively reduced to the corresponding saturated cyclic ethers and N-protected cyclic amines. The 2,4-cis and 2,5-cis pyrrolidine derivatives are produced with high diastereoselectivity. Taking advantage of this selectivity, the 2,5-cis-disubstituted prolinol was also synthesized from glutamic acid in the optically active form.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/26769"}, {"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://dx.doi.org/10.1021/acscatal.7b00403"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications"}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u201cThis document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Catalysis], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-ccnW7GCz94tz5qnyYxff].\u201d"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "2155-5435", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Shibuya, Masatoshi"}], "nameIdentifiers": [{"nameIdentifier": "72669", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fujita, Shoji"}], "nameIdentifiers": [{"nameIdentifier": "72670", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Abe, Masanori"}], "nameIdentifiers": [{"nameIdentifier": "72671", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamamoto, Yoshihiko"}], "nameIdentifiers": [{"nameIdentifier": "72672", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-04-07"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "ACS_catalysis_shibuya_rev2.pdf", "filesize": [{"value": "991.3 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 991300.0, "url": {"label": "ACS_catalysis_shibuya_rev2.pdf \u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2018/04/07", "url": "https://nagoya.repo.nii.ac.jp/record/24552/files/ACS_catalysis_shibuya_rev2.pdf"}, "version_id": "630bb5d9-3480-492d-bd92-c2417f0cdc32"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "alkyne", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Br\u00f8nsted acid", "subitem_subject_scheme": "Other"}, {"subitem_subject": "electrophilic activation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "hydroalkoxylation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "hydroamination", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Br\u00f8nsted Acid/Silane Catalytic System for Intramolecular Hydroalkoxylation and Hydroamination of Unactivated Alkynes", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Br\u00f8nsted Acid/Silane Catalytic System for Intramolecular Hydroalkoxylation and Hydroamination of Unactivated Alkynes"}]}, "item_type_id": "10", "owner": "1", "path": ["1903/1904/1905"], "permalink_uri": "http://hdl.handle.net/2237/26769", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2017-07-05"}, "publish_date": "2017-07-05", "publish_status": "0", "recid": "24552", "relation": {}, "relation_version_is_last": true, "title": ["Br\u00f8nsted Acid/Silane Catalytic System for Intramolecular Hydroalkoxylation and Hydroamination of Unactivated Alkynes"], "weko_shared_id": null}