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Decoupling between the Temperature-Dependent Structural Relaxation and Shear Viscosity of Concentrated Lithium Electrolyte
http://hdl.handle.net/2237/27253
http://hdl.handle.net/2237/272535a54d814-805c-4318-b30c-2b67f3106060
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
manu-accepted.pdf ファイル公開日:2018/08/25 (339.8 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2018-01-10 | |||||
| タイトル | ||||||
| タイトル | Decoupling between the Temperature-Dependent Structural Relaxation and Shear Viscosity of Concentrated Lithium Electrolyte | |||||
| 言語 | en | |||||
| 著者 |
Yamaguchi, Tsuyoshi
× Yamaguchi, Tsuyoshi× Yoshida, Koji× Yamaguchi, Toshio× Nagao, Michihiro× Faraone, Antonio× Seki, Shiro |
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| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 権利 | ||||||
| 言語 | en | |||||
| 権利情報 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in [JOURNAL OF PHYSICAL CHEMISTRY B], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-DjEaUiFwzyjxZQFItTyh].” | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The intermediate scattering functions of concentrated solutions of LiPF6 in propylene carbonate (PC) were measured at various temperatures, two different wavenumbers, and three different concentrations using neutron spin echo (NSE) spectroscopy. The temperature dependence of the relaxation time was larger than that of the steady-state shear viscosity in all cases. The shear relaxation spectra were also determined at different temperatures. The normalized spectra reduced to a master curve when the frequency was multiplied by the steady-state shear viscosity, indicating that the temperature dependence of the steady-state shear viscosity can be explained by that of the relaxation time of the shear stress. It is thus suggested that the dynamics of the shear stress is decoupled from the structural dynamics on the molecular scale. | |||||
| 言語 | en | |||||
| 出版者 | ||||||
| 出版者 | ACS Publications | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1021/acs.jpcb.7b04633 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 1520-6106 | |||||
| 書誌情報 |
en : JOURNAL OF PHYSICAL CHEMISTRY B 巻 121, 号 37, p. 8767-8773, 発行日 2017-08-25 |
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| 著者版フラグ | ||||||
| 値 | author | |||||
| URI | ||||||
| 識別子 | http://doi.org/10.1021/acs.jpcb.7b04633 | |||||
| 識別子タイプ | DOI | |||||
| URI | ||||||
| 識別子 | http://hdl.handle.net/2237/27253 | |||||
| 識別子タイプ | HDL | |||||
