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Design and properties of supramolecular elastomers
http://hdl.handle.net/2237/27356
http://hdl.handle.net/2237/273566b58eebc-6a00-4009-9d4d-6f1b7721e40e
名前 / ファイル | ライセンス | アクション |
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Kajita_Noro_Matsushita_for_Polymer_feature_article_revised.pdf ファイル公開: 2019/3/8 (2.7 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-02-05 | |||||
タイトル | ||||||
タイトル | Design and properties of supramolecular elastomers | |||||
言語 | en | |||||
著者 |
Kajita, Takato
× Kajita, Takato× Noro, Atsushi× Matsushita, Yushu |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | © 2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Supramolecular polymer | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Supramolecular cross-link | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Supramolecular elastomer | |||||
抄録 | ||||||
内容記述 | Supramolecular elastomers are supramolecular soft polymeric materials with both transient cross-links and (semi)permanent cross-links, where transient cross-links have a finite relaxation time and are typically composed of noncovalent bonds such as hydrogen bonds, metal–ligand coordination bonds, etc., whereas (semi)permanent cross-links such as covalent bonds, crystalline segments and glassy hard domains have an infinite relaxation time. Excellent elastomeric properties were induced by a combination of all the above molecular features. However, if soft polymeric materials have only supramolecular/transient cross-links with a finite relaxation time, the materials eventually flow within a finite time and cannot behave as elastomers; in other words, they are merely supramolecular polymers that have only transient cross-links or bonds. Therefore, the key to preparing higher-performance supramolecular elastomers is their molecular design. Here, we firstly review the fundamental design of supramolecular polymers to make the differences between supramolecular polymers and supramolecular elastomers clear. Second, we discuss the simultaneous incorporation of (semi)permanent cross-links and supramolecular cross-links into polymeric materials to prepare supramolecular elastomers. Finally we summarized their properties and potential applications. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | Available online 8 March 2017 | |||||
言語 | en | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Elsevier | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1016/j.polymer.2017.03.010 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 0032-3861 | |||||
書誌情報 |
en : POLYMER 巻 128, 号 16, p. 297-310, 発行日 2017-10 |
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著者版フラグ | ||||||
値 | author | |||||
URI | ||||||
識別子 | http://doi.org/10.1016/j.polymer.2017.03.010 | |||||
識別子タイプ | DOI | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/27356 | |||||
識別子タイプ | HDL |