{"_buckets": {"deposit": "c6a35e0c-dacc-442b-a226-cefe58af188b"}, "_deposit": {"id": "25700", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "25700"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00025700"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2017-12", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "20", "bibliographicPageEnd": "2940", "bibliographicPageStart": "2936", "bibliographicVolumeNumber": "28", "bibliographic_titles": [{"bibliographic_title": "Synlett"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The formal cross-dehydrogenative coupling of triarylmethanes with arenes promoted by triflic acid and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone is described. This method provides a variety of tetraarylmethane derivatives in good to excellent yields from triarylmethanes that can be readily prepared by our previous methods. Control experiments suggest a possible catalytic cycle involving the generation of a trityl cation intermediate followed by nucleophilic addition of the arene.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2018-12-01", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Georg Thieme Verlag"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://doi.org/10.1055/s-0036-1588563", "subitem_relation_type_select": "DOI"}}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0936-5214", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Nambo, Masakazu"}], "nameIdentifiers": [{"nameIdentifier": "76108", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yim, Jacky C.-H."}], "nameIdentifiers": [{"nameIdentifier": "76109", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fowler, Kevin G."}], "nameIdentifiers": [{"nameIdentifier": "76110", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Crudden, Cathleen M."}], "nameIdentifiers": [{"nameIdentifier": "76111", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-12-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "repository.pdf", "filesize": [{"value": "467.5 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 467500.0, "url": {"label": "repository", "url": "https://nagoya.repo.nii.ac.jp/record/25700/files/repository.pdf"}, "version_id": "1e98f18f-4124-46b8-bd09-7ea16795c7d3"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "cross-coupling", "subitem_subject_scheme": "Other"}, {"subitem_subject": "dehydrogenation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "tetraarylmethanes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "triarylmethanes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "arylation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "organocatalysis", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of Tetraarylmethanes by the Triflic Acid-Promoted Formal Cross-Dehydrogenative Coupling of Triarylmethanes with Arenes", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Synthesis of Tetraarylmethanes by the Triflic Acid-Promoted Formal Cross-Dehydrogenative Coupling of Triarylmethanes with Arenes"}]}, "item_type_id": "10", "owner": "1", "path": ["1935/1936/1937"], "permalink_uri": "http://hdl.handle.net/2237/00027910", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2018-04-17"}, "publish_date": "2018-04-17", "publish_status": "0", "recid": "25700", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of Tetraarylmethanes by the Triflic Acid-Promoted Formal Cross-Dehydrogenative Coupling of Triarylmethanes with Arenes"], "weko_shared_id": null}