{"_buckets": {"deposit": "f7a6f8b3-a942-4a00-8da2-427c31bc2b82"}, "_deposit": {"id": "25739", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "25739"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00025739", "sets": ["696"]}, "author_link": ["76306", "76307", "76308", "76309"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-01-26", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "5", "bibliographicPageEnd": "1341", "bibliographicPageStart": "1337", "bibliographicVolumeNumber": "57", "bibliographic_titles": [{"bibliographic_title": "Angewandte Chemie International Edition", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The synthesis and structural analysis of a quintuple [6]helicene with a corannulene core is reported. The compound was synthesized from corannulene in three steps including a five‐fold intramolecular direct arylation. X‐ray crystallographic analysis revealed a C5‐symmetric propeller‐shaped structure and one‐dimensional alignment in the solid state. The enantiomers of the quintuple [6]helicene were successfully separated by HPLC, and the chirality of the two fractions was identified by CD spectroscopy. A kinetic study yielded a racemization barrier of 34.2 kcal mol^−1, which is slightly lower than that of pristine [6]helicene. DFT calculations indicate a rapid bowl‐to‐bowl inversion of the corannulene moiety and a step‐by‐step chiral inversion pathway for the five [6]helicene moieties.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "ファイル公開：2019-01-26 ", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/anie.201711985", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "This is the peer reviewed version of the following article: [K. Kato, Y. Segawa, L. T. Scott, K. Itami, Angew. Chem. Int. Ed. 2018, 57, 1337.], which has been published in final form at [http://doi.org/10.1002/anie.201711985]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "14337851", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kato, Kenta", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "76306", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Segawa, Yasutomo", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "76307", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Scott, Lawrence T.", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "76308", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Itami, Kenichiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "76309", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-01-26"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "KatoCQH_20171226.pdf", "filesize": [{"value": "1.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 1100000.0, "url": {"label": "KatoCQH_20171226", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/25739/files/KatoCQH_20171226.pdf"}, "version_id": "5c23c83b-f73f-4f0c-9497-fc582b0c2ec4"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "arenes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "corannulenes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "helicenes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "polycycles", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "A Quintuple [6]Helicene with a Corannulene Core as a C5-Symmetric Propeller-Shaped π-System", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "A Quintuple [6]Helicene with a Corannulene Core as a C5-Symmetric Propeller-Shaped π-System", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["696"], "permalink_uri": "http://hdl.handle.net/2237/00027944", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2018-05-08"}, "publish_date": "2018-05-08", "publish_status": "0", "recid": "25739", "relation": {}, "relation_version_is_last": true, "title": ["A Quintuple [6]Helicene with a Corannulene Core as a C5-Symmetric Propeller-Shaped π-System"], "weko_shared_id": -1}