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  1. D400 創薬科学研究科
  2. D400a 雑誌掲載論文
  3. 学術雑誌

Synthetic Studies of Haliclonin A : Construction of the 3-Azabicyclo[3.3.1]nonane Skeleton with a Bridge that Forms the 17-Membered Ring

http://hdl.handle.net/2237/00028342
13241f26-aaf3-4b1d-883a-49493edd20d9
名前 / ファイル ライセンス アクション
20171122_rev.pdf 20171122_rev (422.1 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2018-07-04
タイトル
タイトル Synthetic Studies of Haliclonin A : Construction of the 3-Azabicyclo[3.3.1]nonane Skeleton with a Bridge that Forms the 17-Membered Ring
著者 Orihara, Kensuke

× Orihara, Kensuke

WEKO 78412

Orihara, Kensuke

Search repository
Kawagishi, Fumiki

× Kawagishi, Fumiki

WEKO 78413

Kawagishi, Fumiki

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Yokoshima, Satoshi

× Yokoshima, Satoshi

WEKO 78414

Yokoshima, Satoshi

Search repository
Fukuyama, Tohru

× Fukuyama, Tohru

WEKO 78415

Fukuyama, Tohru

Search repository
キーワード
主題Scheme Other
主題 alkaloids
キーワード
主題Scheme Other
主題 conjugate addition
キーワード
主題Scheme Other
主題 heterocycles
キーワード
主題Scheme Other
主題 hydride shift
キーワード
主題Scheme Other
主題 macrocycles
キーワード
主題Scheme Other
主題 marine natural products
キーワード
主題Scheme Other
主題 ring-closing metathesis
抄録
内容記述 The core structure of haliclonin A, a 3-azabicyclo[3.3.1]­nonane with a bridge that forms a 17-membered ring, was constructed. The synthesis features a ring-closing metathesis that constructs the macrocyclic ring, the stereoselective introduction of carbon units via the intra­molecular cyclopropanation of a diazoester, the conjugate addition of an organocopper reagent, and the formation of 3-azabi­cyclo­[3.3.1]­nonane skeleton via an unexpected 1,5-hydride shift.
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2019-04-01
内容記述タイプ Other
出版者
出版者 Georg Thieme Verlag
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.1055/s-0037-1609150
ISSN
収録物識別子タイプ ISSN
収録物識別子 0936-5214
書誌情報 Synlett

巻 29, 号 6, p. 769-772, 発行日 2018-04
著者版フラグ
値 author
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