{"_buckets": {"deposit": "22cc65e4-2d64-4117-986e-bc760c842de9"}, "_deposit": {"id": "26138", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "26138"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00026138"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-04", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "6", "bibliographicPageEnd": "772", "bibliographicPageStart": "769", "bibliographicVolumeNumber": "29", "bibliographic_titles": [{"bibliographic_title": "Synlett"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The core structure of haliclonin A, a 3-azabicyclo[3.3.1]\u00adnonane with a bridge that forms a 17-membered ring, was constructed. The synthesis features a ring-closing metathesis that constructs the macrocyclic ring, the stereoselective introduction of carbon units via the intra\u00admolecular cyclopropanation of a diazoester, the conjugate addition of an organocopper reagent, and the formation of 3-azabi\u00adcyclo\u00ad[3.3.1]\u00adnonane skeleton via an unexpected 1,5-hydride shift.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2019-04-01", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Georg Thieme Verlag"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1055/s-0037-1609150", "subitem_relation_type_select": "DOI"}}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0936-5214", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Orihara, Kensuke"}], "nameIdentifiers": [{"nameIdentifier": "78412", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kawagishi, Fumiki"}], "nameIdentifiers": [{"nameIdentifier": "78413", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yokoshima, Satoshi"}], "nameIdentifiers": [{"nameIdentifier": "78414", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fukuyama, Tohru"}], "nameIdentifiers": [{"nameIdentifier": "78415", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-04-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "20171122_rev.pdf", "filesize": [{"value": "422.1 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 422100.0, "url": {"label": "20171122_rev", "url": "https://nagoya.repo.nii.ac.jp/record/26138/files/20171122_rev.pdf"}, "version_id": "61f3f960-e092-46f3-a267-3db3c4874aba"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "alkaloids", "subitem_subject_scheme": "Other"}, {"subitem_subject": "conjugate addition", "subitem_subject_scheme": "Other"}, {"subitem_subject": "heterocycles", "subitem_subject_scheme": "Other"}, {"subitem_subject": "hydride shift", "subitem_subject_scheme": "Other"}, {"subitem_subject": "macrocycles", "subitem_subject_scheme": "Other"}, {"subitem_subject": "marine natural products", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ring-closing metathesis", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthetic Studies of Haliclonin A : Construction of the 3-Azabicyclo[3.3.1]nonane Skeleton with a Bridge that Forms the 17-Membered Ring", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Synthetic Studies of Haliclonin A : Construction of the 3-Azabicyclo[3.3.1]nonane Skeleton with a Bridge that Forms the 17-Membered Ring"}]}, "item_type_id": "10", "owner": "1", "path": ["1903/1904/1905"], "permalink_uri": "http://hdl.handle.net/2237/00028342", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2018-07-04"}, "publish_date": "2018-07-04", "publish_status": "0", "recid": "26138", "relation": {}, "relation_version_is_last": true, "title": ["Synthetic Studies of Haliclonin A : Construction of the 3-Azabicyclo[3.3.1]nonane Skeleton with a Bridge that Forms the 17-Membered Ring"], "weko_shared_id": null}