{"_buckets": {"deposit": "22cc65e4-2d64-4117-986e-bc760c842de9"}, "_deposit": {"id": "26138", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "26138"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00026138", "sets": ["1905"]}, "author_link": ["78412", "78413", "78414", "78415"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-04", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "6", "bibliographicPageEnd": "772", "bibliographicPageStart": "769", "bibliographicVolumeNumber": "29", "bibliographic_titles": [{"bibliographic_title": "Synlett", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The core structure of haliclonin A, a 3-azabicyclo[3.3.1]­nonane with a bridge that forms a 17-membered ring, was constructed. The synthesis features a ring-closing metathesis that constructs the macrocyclic ring, the stereoselective introduction of carbon units via the intra­molecular cyclopropanation of a diazoester, the conjugate addition of an organocopper reagent, and the formation of 3-azabi­cyclo­[3.3.1]­nonane skeleton via an unexpected 1,5-hydride shift.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "ファイル公開：2019-04-01", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Georg Thieme Verlag", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1055/s-0037-1609150", "subitem_relation_type_select": "DOI"}}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0936-5214", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Orihara, Kensuke", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "78412", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kawagishi, Fumiki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "78413", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yokoshima, Satoshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "78414", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fukuyama, Tohru", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "78415", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-04-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "20171122_rev.pdf", "filesize": [{"value": "422.1 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 422100.0, "url": {"label": "20171122_rev", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/26138/files/20171122_rev.pdf"}, "version_id": "61f3f960-e092-46f3-a267-3db3c4874aba"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "alkaloids", "subitem_subject_scheme": "Other"}, {"subitem_subject": "conjugate addition", "subitem_subject_scheme": "Other"}, {"subitem_subject": "heterocycles", "subitem_subject_scheme": "Other"}, {"subitem_subject": "hydride shift", "subitem_subject_scheme": "Other"}, {"subitem_subject": "macrocycles", "subitem_subject_scheme": "Other"}, {"subitem_subject": "marine natural products", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ring-closing metathesis", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthetic Studies of Haliclonin A : Construction of the 3-Azabicyclo[3.3.1]nonane Skeleton with a Bridge that Forms the 17-Membered Ring", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Synthetic Studies of Haliclonin A : Construction of the 3-Azabicyclo[3.3.1]nonane Skeleton with a Bridge that Forms the 17-Membered Ring", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["1905"], "permalink_uri": "http://hdl.handle.net/2237/00028342", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2018-07-04"}, "publish_date": "2018-07-04", "publish_status": "0", "recid": "26138", "relation": {}, "relation_version_is_last": true, "title": ["Synthetic Studies of Haliclonin A : Construction of the 3-Azabicyclo[3.3.1]nonane Skeleton with a Bridge that Forms the 17-Membered Ring"], "weko_shared_id": -1}