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Synthetic Studies of Haliclonin A : Construction of the 3-Azabicyclo[3.3.1]nonane Skeleton with a Bridge that Forms the 17-Membered Ring
http://hdl.handle.net/2237/00028342
13241f26-aaf3-4b1d-883a-49493edd20d9
名前 / ファイル | ライセンス | アクション | |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-07-04 | |||||
タイトル | ||||||
タイトル | Synthetic Studies of Haliclonin A : Construction of the 3-Azabicyclo[3.3.1]nonane Skeleton with a Bridge that Forms the 17-Membered Ring | |||||
著者 |
Orihara, Kensuke
× Orihara, Kensuke× Kawagishi, Fumiki× Yokoshima, Satoshi× Fukuyama, Tohru |
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キーワード | ||||||
主題Scheme | Other | |||||
主題 | alkaloids | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | conjugate addition | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | heterocycles | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | hydride shift | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | macrocycles | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | marine natural products | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | ring-closing metathesis | |||||
抄録 | ||||||
内容記述 | The core structure of haliclonin A, a 3-azabicyclo[3.3.1]nonane with a bridge that forms a 17-membered ring, was constructed. The synthesis features a ring-closing metathesis that constructs the macrocyclic ring, the stereoselective introduction of carbon units via the intramolecular cyclopropanation of a diazoester, the conjugate addition of an organocopper reagent, and the formation of 3-azabicyclo[3.3.1]nonane skeleton via an unexpected 1,5-hydride shift. | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2019-04-01 | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
出版者 | Georg Thieme Verlag | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
DOI | ||||||
関連識別子 | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1055/s-0037-1609150 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0936-5214 | |||||
書誌情報 |
Synlett 巻 29, 号 6, p. 769-772, 発行日 2018-04 |
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著者版フラグ | ||||||
値 | author |