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Formation of Rhodium Metal Ensembles that Facilitate Nitric Oxide Reduction over Rhodium/Ceria in a Stoichiometric Nitric Oxide-Carbon Monoxide-Propene-Oxygen Reaction
http://hdl.handle.net/2237/00028459
http://hdl.handle.net/2237/000284592790d512-5478-408b-bb89-b0d25ba8d776
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
CCTC-S-17-02037 (943.0 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2018-08-10 | |||||
| タイトル | ||||||
| タイトル | Formation of Rhodium Metal Ensembles that Facilitate Nitric Oxide Reduction over Rhodium/Ceria in a Stoichiometric Nitric Oxide-Carbon Monoxide-Propene-Oxygen Reaction | |||||
| 言語 | en | |||||
| 著者 |
Ohyama, Junya
× Ohyama, Junya× Nishiyama, Takumi× Satsuma, Atsushi |
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| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 権利 | ||||||
| 言語 | en | |||||
| 権利情報 | This is the peer reviewed version of the following article: [J. Ohyama, T. Nishiyama, A. Satsuma, ChemCatChem 2018, 10, 1651.], which has been published in final form at [https://doi.org/10.1002/cctc.201701842]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | A series of ceria‐supported Rh nanoparticles (NPs) that have various particle sizes of 2–7 nm was prepared to investigate the size effect of Rh NPs on NO reduction in NO–CO–C3H6–O2 under stoichiometric conditions. The turnover frequency (TOF) for NO reduction on Rh NPs increased drastically according to their particle size. The strong size dependence of the TOF was attributed to the oxidation states of Rh NPs but not to particle geometries, which include fractions of surface local sites (e.g., corner, edge, plane) and the surface crystal structures (e.g., Rh(1 1 1), (1 0 0)). The variation of the TOF with the Rh metal fraction suggested that Rh metal ensembles are highly active species for NO reduction. | |||||
| 言語 | en | |||||
| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | ファイル公開：2019-04-09 | |||||
| 言語 | ja | |||||
| 出版者 | ||||||
| 出版者 | Wiley | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1002/cctc.201701842 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 1867-3880 | |||||
| 書誌情報 |
en : ChemCatChem 巻 10, 号 7, p. 1651-1656, 発行日 2018-04-09 |
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| 著者版フラグ | ||||||
| 値 | author | |||||
