{"_buckets": {"deposit": "f471622c-7d73-4fdd-bd64-b4c78950821c"}, "_deposit": {"id": "26369", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "26369"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00026369"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-06-27", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "26", "bibliographicPageEnd": "2484", "bibliographicPageStart": "2477", "bibliographicVolumeNumber": "59", "bibliographic_titles": [{"bibliographic_title": "Tetrahedron Letters"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Acidic 1,3-azolium salts are prepared from Br\u00f8nsted acids and 1,3-azoles such as imidazole, thiazole, and oxazole. Acidic imidazolium salts are frequently employed as promoters for the synthesis of nucleotides using the phosphoramidite method in a solution phase. Recently, it was revealed that thiazolium and oxazolium salts catalyzed Vorbr\u00fcggen-type N-glycosylation reactions to give nucleosides. These reactivities are attributed to the stronger Br\u00f8nsted acidities of the thiazolium and oxazolium salts relative to those of the imidazolium salts. This digest focuses on recent progress in the applicability of acidic 1,3-azolium salts as promoters in the solution-phase synthesis of nucleosides and nucleotides.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2020-06-27", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Elsevier"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1016/j.tetlet.2018.03.074", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u00a9 2018. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "0040-4039", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Tsukamoto, Masaki"}], "nameIdentifiers": [{"nameIdentifier": "85288", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Oyama, Kin-ichi"}], "nameIdentifiers": [{"nameIdentifier": "85289", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-06-27"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "TL2018v59p2477_RevisedMN_ToCL.pdf", "filesize": [{"value": "857.2 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 857200.0, "url": {"label": "TL2018v59p2477_RevisedMN_ToCL", "url": "https://nagoya.repo.nii.ac.jp/record/26369/files/TL2018v59p2477_RevisedMN_ToCL.pdf"}, "version_id": "53e9dbd0-cd9d-4fcc-9752-795bba5bd02a"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Acidic 1,3-azolium salt", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Nucleoside", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Nucleotide", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Acidic imidazolium salt", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Acidic oxazolium salt", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Recent application of acidic 1,3-azolium salts as promoters in the solution-phase synthesis of nucleosides and nucleotides", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Recent application of acidic 1,3-azolium salts as promoters in the solution-phase synthesis of nucleosides and nucleotides"}]}, "item_type_id": "10", "owner": "1", "path": ["312/313/314"], "permalink_uri": "http://hdl.handle.net/2237/00028572", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2018-09-12"}, "publish_date": "2018-09-12", "publish_status": "0", "recid": "26369", "relation": {}, "relation_version_is_last": true, "title": ["Recent application of acidic 1,3-azolium salts as promoters in the solution-phase synthesis of nucleosides and nucleotides"], "weko_shared_id": null}