{"_buckets": {"deposit": "d47b53fc-b44e-4b9e-8d0a-d1431cda05ff"}, "_deposit": {"id": "27049", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "27049"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00027049"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-11", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "18", "bibliographicPageEnd": "2380", "bibliographicPageStart": "2377", "bibliographicVolumeNumber": "29", "bibliographic_titles": [{"bibliographic_title": "Synlett"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A total synthesis of lycoposerramine-R was accomplished. The synthesis featured a Claisen\u2013Ireland rearrangement to install a two-carbon unit, and a hetero-Diels\u2013Alder reaction to form a cyclic enol ether that reacted with an ethynyl group to construct a cis-hydrindane core containing a quaternary carbon. A 2-pyridone synthesis using 2-(phenylsulfinyl)acetamide was used to complete the synthesis.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2019-11-01", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Georg Thieme Verlag"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1055/s-0037-1611024", "subitem_relation_type_select": "DOI"}}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "0936-5214", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Watanabe, Shinya"}], "nameIdentifiers": [{"nameIdentifier": "88608", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishikawa, Masatsugu"}], "nameIdentifiers": [{"nameIdentifier": "88609", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nomura, Toshimune"}], "nameIdentifiers": [{"nameIdentifier": "88610", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fukuyama, Tohru"}], "nameIdentifiers": [{"nameIdentifier": "88611", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yokoshima, Satoshi"}], "nameIdentifiers": [{"nameIdentifier": "88612", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-11-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "20180831_watanabe.pdf", "filesize": [{"value": "301.2 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 301200.0, "url": {"label": "20180831_watanabe", "url": "https://nagoya.repo.nii.ac.jp/record/27049/files/20180831_watanabe.pdf"}, "version_id": "3f7750d3-5654-4aca-abc3-83dec34e1bf7"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "alkaloids", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Diels\u2013Alder reaction", "subitem_subject_scheme": "Other"}, {"subitem_subject": "total synthesis", "subitem_subject_scheme": "Other"}, {"subitem_subject": "gold catalysis", "subitem_subject_scheme": "Other"}, {"subitem_subject": "alkaloids", "subitem_subject_scheme": "Other"}, {"subitem_subject": "rearrangement", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Total Synthesis of Lycoposerramine-R", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Total Synthesis of Lycoposerramine-R"}]}, "item_type_id": "10", "owner": "1", "path": ["1903/1904/1905"], "permalink_uri": "http://hdl.handle.net/2237/00029249", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2019-02-06"}, "publish_date": "2019-02-06", "publish_status": "0", "recid": "27049", "relation": {}, "relation_version_is_last": true, "title": ["Total Synthesis of Lycoposerramine-R"], "weko_shared_id": null}