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  1. H120 物質科学国際研究センター
  2. H120a 雑誌掲載論文
  3. 学術雑誌

Acceptor-Controlled Transfer Dehydration of Amides to Nitriles

http://hdl.handle.net/2237/00030512
http://hdl.handle.net/2237/00030512
eb46e7f6-779d-40c7-87ef-f83a005d4120
名前 / ファイル ライセンス アクション
9603_ANA_Text.pdf 9603_ANA_Text (656.7 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2019-07-08
タイトル
タイトル Acceptor-Controlled Transfer Dehydration of Amides to Nitriles
言語 en
著者 Okabe, Hiroyuki

× Okabe, Hiroyuki

WEKO 92487

en Okabe, Hiroyuki

Search repository
Naraoka, Asuka

× Naraoka, Asuka

WEKO 92488

en Naraoka, Asuka

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Isogawa, Takahiro

× Isogawa, Takahiro

WEKO 92489

en Isogawa, Takahiro

Search repository
Oishi, Shunsuke

× Oishi, Shunsuke

WEKO 92490

en Oishi, Shunsuke

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Naka, Hiroshi

× Naka, Hiroshi

WEKO 92491

en Naka, Hiroshi

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-7WWfTw3cdW33V2d27WiB].”
抄録
内容記述 Palladium-catalyzed dehydration of primary amides to nitriles efficiently proceeds under mild, aqueous conditions via the use of dichloroacetonitrile as a water acceptor. A key to the design of this transfer dehydration catalysis is the identification of an efficient water acceptor, dichloroacetonitrile, that preferentially reacts with amides over other polar functional groups with the aid of the Pd catalyst and makes the desired scheme exergonic, thereby driving the dehydration.
言語 en
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2020-06-21
言語 ja
内容記述タイプ Other
出版者
言語 en
出版者 ACS Publications
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1021/acs.orglett.9b01657
ISSN(print)
収録物識別子タイプ PISSN
収録物識別子 1523-7060
書誌情報 en : Organic Letters

巻 21, 号 12, p. 4767-4770, 発行日 2019-06-21
著者版フラグ
値 author
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