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Acceptor-Controlled Transfer Dehydration of Amides to Nitriles
http://hdl.handle.net/2237/00030512
http://hdl.handle.net/2237/00030512eb46e7f6-779d-40c7-87ef-f83a005d4120
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
9603_ANA_Text (656.7 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2019-07-08 | |||||
| タイトル | ||||||
| タイトル | Acceptor-Controlled Transfer Dehydration of Amides to Nitriles | |||||
| 言語 | en | |||||
| 著者 |
Okabe, Hiroyuki
× Okabe, Hiroyuki× Naraoka, Asuka× Isogawa, Takahiro× Oishi, Shunsuke× Naka, Hiroshi |
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| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 権利 | ||||||
| 言語 | en | |||||
| 権利情報 | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-7WWfTw3cdW33V2d27WiB].” | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Palladium-catalyzed dehydration of primary amides to nitriles efficiently proceeds under mild, aqueous conditions via the use of dichloroacetonitrile as a water acceptor. A key to the design of this transfer dehydration catalysis is the identification of an efficient water acceptor, dichloroacetonitrile, that preferentially reacts with amides over other polar functional groups with the aid of the Pd catalyst and makes the desired scheme exergonic, thereby driving the dehydration. | |||||
| 言語 | en | |||||
| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | ファイル公開：2020-06-21 | |||||
| 言語 | ja | |||||
| 出版者 | ||||||
| 出版者 | ACS Publications | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | journal article | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1021/acs.orglett.9b01657 | |||||
| ISSN（print） | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 1523-7060 | |||||
| 書誌情報 |
en : Organic Letters 巻 21, 号 12, p. 4767-4770, 発行日 2019-06-21 |
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| 著者版フラグ | ||||||
| 値 | author | |||||
