{"_buckets": {"deposit": "e1853b60-2517-486c-b971-53f1ffba39b1"}, "_deposit": {"id": "28346", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "28346"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00028346"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-03", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "190", "bibliographicPageStart": "183", "bibliographicVolumeNumber": "161", "bibliographic_titles": [{"bibliographic_title": "Polymer Degradation and Stability"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Valencene, a naturally occurring sesquiterpene that can be obtained from various citrus fruits, was copolymerized as an unconjugated 1,1-disubstituted bulky vinyl monomer by radical copolymerization with conjugated monomers possessing electron-withdrawing substituents, such as maleimides, acrylates, methacrylates, acrylonitrile, and methacrylonitrile, in toluene and PhC(CF3)2OH. The fluorinated alcohol increased the copolymerizability, as in the radical copolymerization of other unconjugated non-polar olefins with those electron-acceptor comonomers. In particular, the copolymerization of valencene and N-phenylmaleimide in PhC(CF3)2OH proceeded via concurrently occurring 1:1 and 1:2 propagation, in which the monomer reactivity ratio of maleimide and valencene to the maleimide radical with the penultimate valencene unit was close to 1 according to a kinetic analysis of the copolymerization based on the penultimate model. Therefore, the copolymerizability of valencene was higher than that of limonene, which is a similar unconjugated 1,1-disubstituted vinyl monomer with a smaller cyclohexenyl substituent that undergoes selective 1:2 radical copolymerization with maleimide derivatives under the same conditions. Reversible addition-fragmentation chain transfer RAFT copolymerization using a trithiocarbonate resulted in copolymers with controlled molecular weights and chain-end groups. The biobased copolymers of valencene and N-phenylmaleimide showed relatively high glass transition temperatures (Tg) of approximately 220\u2013240\u202f\u00b0C and relatively high thermal stability with 5% decomposition temperatures (Td5) of approximately 330\u2013340\u202f\u00b0C due to their rigid main-chain structures.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2021-03-01", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Elsevier"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1016/j.polymdegradstab.2019.01.025", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u00a9 2019. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "0141-3910", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hashimoto, Hiroaki"}], "nameIdentifiers": [{"nameIdentifier": "92573", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Takeshima, Hisaaki"}], "nameIdentifiers": [{"nameIdentifier": "92574", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nagai, Tomonari"}], "nameIdentifiers": [{"nameIdentifier": "92575", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Uchiyama, Mineto"}], "nameIdentifiers": [{"nameIdentifier": "92576", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Satoh, Kotaro"}], "nameIdentifiers": [{"nameIdentifier": "92577", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kamigaito, Masami"}], "nameIdentifiers": [{"nameIdentifier": "92578", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-03-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "POLYMER_DEGRADATION_AND_STABILITY161_2019_183-190.pdf", "filesize": [{"value": "3.2 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 3200000.0, "url": {"label": "POLYMER_DEGRADATION_AND_STABILITY161_2019_183-190", "url": "https://nagoya.repo.nii.ac.jp/record/28346/files/POLYMER_DEGRADATION_AND_STABILITY161_2019_183-190.pdf"}, "version_id": "f60aa323-7b74-47b0-81cd-afc817e4b882"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Terpene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Orange", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Radical copolymerization", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Alternating copolymerization", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Thermal properties", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Valencene as a naturally occurring sesquiterpene monomer for radical copolymerization with maleimide to induce concurrent 1:1 and 1:2 propagation", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Valencene as a naturally occurring sesquiterpene monomer for radical copolymerization with maleimide to induce concurrent 1:1 and 1:2 propagation"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/00030541", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2019-07-11"}, "publish_date": "2019-07-11", "publish_status": "0", "recid": "28346", "relation": {}, "relation_version_is_last": true, "title": ["Valencene as a naturally occurring sesquiterpene monomer for radical copolymerization with maleimide to induce concurrent 1:1 and 1:2 propagation"], "weko_shared_id": null}