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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

An enantioselective oxidative coupling reaction of 2-naphthol derivatives catalyzed by chiral diphosphine oxide–iron(ii) complexes

http://hdl.handle.net/2237/00031497
bd66b340-2ab4-45c9-a2d7-5799eeffa420
名前 / ファイル ライセンス アクション
Manuscript.pdf Manuscript (1.4 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2020-02-12
タイトル
タイトル An enantioselective oxidative coupling reaction of 2-naphthol derivatives catalyzed by chiral diphosphine oxide–iron(ii) complexes
著者 Horibe, Takahiro

× Horibe, Takahiro

WEKO 95964

Horibe, Takahiro

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Nakagawa, Keita

× Nakagawa, Keita

WEKO 95965

Nakagawa, Keita

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Hazeyama, Takashi

× Hazeyama, Takashi

WEKO 95966

Hazeyama, Takashi

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Takeda, Kazuki

× Takeda, Kazuki

WEKO 95967

Takeda, Kazuki

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Ishihara, Kazuaki

× Ishihara, Kazuaki

WEKO 95968

Ishihara, Kazuaki

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抄録
内容記述 An enantioselective oxidative coupling of 2-naphthol derivatives is developed with the use of chiral Fe(II)–diphosphine oxide complexes. Optically active 1,1-bi-2-naphthol derivatives can be synthesized in high yields when a 2 : 1 complex of (S)-xylyl-iPrO-BIPHEP-oxide and Fe(OTf)2 is used in the presence of t-butyl hydroperoxide as an oxidant. The non-linear effect, X-ray crystal structure and ESI-MS suggest that a 2 : 1 complex of (S)-xylyl-iPrO-BIPHEP-oxide and Fe(OTf)2 is a pre-catalyst for a Fe(III)/Fe(IV) redox cycle.
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2020/11/25
内容記述タイプ Other
出版者
出版者 Royal Society of Chemistry
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.1039/C9CC07834G
ISSN(print)
収録物識別子タイプ ISSN
収録物識別子 1359-7345
書誌情報 Chemical Communications

巻 55, 号 91, p. 13677-13680, 発行日 2019-11
著者版フラグ
値 author
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