{"_buckets": {"deposit": "8015c8ff-d45b-4fc8-a81f-97fcc8f7d356"}, "_deposit": {"id": "30129", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "30129"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00030129"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-02-26", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "12", "bibliographicPageEnd": "2760", "bibliographicPageStart": "2754", "bibliographicVolumeNumber": "26", "bibliographic_titles": [{"bibliographic_title": "Chemistry\u2013A European Journal"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "N\u2010Alkylation significantly changes the electronic and optical properties, as well as the reactivity of nitrogen\u2010containing \u03c0\u2010conjugated molecules. In this study, it is found that treating 5,15\u2010diazaporphyrins with methyl triflate selectively affords the corresponding N \u2010methyl\u20105,15\u2010diazaporphyrinium cations in good yield. N\u2010Methylation substantially alters the electronic properties and reactivity of diazaporphyrins. The electron\u2010accepting properties of the N \u2010methyl\u20105,15\u2010diazaporphyrinium cations are enhanced due to their lowered LUMO level. Stabilization of the LUMO energy enables regio\u2010 and stereoselective Diels\u2013Alder reactions of the cationic diazaporphyrin with cyclopentadiene. N\u2010Methylation also enhances the acidity of the inner NH protons, and thus, allows facile deprotonation to provide nitrogen\u2010substituted isoporphyrin analogues with only one NH group in the central cavity.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2021-02-26", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/chem.201905402", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [W. X. Chia, M. Nishijo, S. Kang, J. Oh, T. Nishimura, H. Omori, J.-F. Longevial, Y. Miyake, D. Kim, H. Shinokubo, Chem. Eur. J. 2020 , 26 , 2754.], which has been published in final form at [https://doi.org/10.1002/chem.201905402]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "0947-6539", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Chia, Wen Xi"}], "nameIdentifiers": [{"nameIdentifier": "99456", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishijo, Mayu"}], "nameIdentifiers": [{"nameIdentifier": "99457", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kang, Seongsoo"}], "nameIdentifiers": [{"nameIdentifier": "99458", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Oh, Juwon"}], "nameIdentifiers": [{"nameIdentifier": "99459", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishimura, Tsubasa"}], "nameIdentifiers": [{"nameIdentifier": "99460", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Omori, Hiroto"}], "nameIdentifiers": [{"nameIdentifier": "99461", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Longevial, Jean\u2010Fran\u00e7ois"}], "nameIdentifiers": [{"nameIdentifier": "99462", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Miyake, Yoshihiro"}], "nameIdentifiers": [{"nameIdentifier": "99463", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kim, Dongho"}], "nameIdentifiers": [{"nameIdentifier": "99464", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shinokubo, Hiroshi"}], "nameIdentifiers": [{"nameIdentifier": "99465", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-02-26"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "manuscript.pdf", "filesize": [{"value": "2.4 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2400000.0, "url": {"label": "manuscript", "url": "https://nagoya.repo.nii.ac.jp/record/30129/files/manuscript.pdf"}, "version_id": "6630c2de-9cdf-42ae-b50d-a7714b71e7a2"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "aromaticity", "subitem_subject_scheme": "Other"}, {"subitem_subject": "conjugation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "cycloaddition", "subitem_subject_scheme": "Other"}, {"subitem_subject": "methylation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "porphyrinoids", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Site\u2010Selective N\u2010Methylation of 5,15\u2010Diazaporphyrins: Reactive Cationic Porphyrinoids that Provide Isoporphyrin Analogues", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Site\u2010Selective N\u2010Methylation of 5,15\u2010Diazaporphyrins: Reactive Cationic Porphyrinoids that Provide Isoporphyrin Analogues"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/00032315", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2020-06-09"}, "publish_date": "2020-06-09", "publish_status": "0", "recid": "30129", "relation": {}, "relation_version_is_last": true, "title": ["Site\u2010Selective N\u2010Methylation of 5,15\u2010Diazaporphyrins: Reactive Cationic Porphyrinoids that Provide Isoporphyrin Analogues"], "weko_shared_id": null}