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  1. B100 理学部/理学研究科
  2. B100a 雑誌掲載論文
  3. 学術雑誌

Metal–Sulfur Compounds in N2 Reduction and Nitrogenase-Related Chemistry

http://hdl.handle.net/2237/00032733
http://hdl.handle.net/2237/00032733
816f1c51-1234-4bac-a19d-75c2be9f7152
名前 / ファイル ライセンス アクション
manuscript-chemrev.pdf manuscript-chemrev (9.2 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2020-10-15
タイトル
タイトル Metal–Sulfur Compounds in N2 Reduction and Nitrogenase-Related Chemistry
言語 en
著者 Tanifuji, Kazuki

× Tanifuji, Kazuki

WEKO 101713

en Tanifuji, Kazuki

Search repository
Ohki, Yasuhiro

× Ohki, Yasuhiro

WEKO 101714

en Ohki, Yasuhiro

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Chemical Reviews], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-WPW3Y6W9CGCCCWAE4QEX].”
抄録
内容記述 Transition metal–sulfur (M–S) compounds are an indispensable means for biological systems to convert N2 into NH3 (biological N2 fixation), and these may have emerged by chemical evolution from a prebiotic N2 fixation system. With a main focus on synthetic species, this article provides a comprehensive review of the chemistry of M–S compounds related to the conversion of N2 and the structures/functions of the nitrogenase cofactors. Three classes of M–S compounds are highlighted here: multinuclear M–S clusters structurally or functionally relevant to the nitrogenase cofactors, mono- and dinuclear transition metal complexes supported by sulfur-containing ligands in N2 and N2Hx (x = 2, 4) chemistry, and metal sulfide-based solid materials employed in the reduction of N2. Fair assessments on these classes of compounds revealed that our understanding is still limited in N2 reduction and related substrate reductions. Our aims of this review are to compile a collection of studies performed at atomic to mesoscopic scales and to present potential opportunities for elucidating the roles of metal and sulfur atoms in the biological N2 fixation that might be helpful for the development of functional materials.
言語 en
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2021-06-24
言語 ja
内容記述タイプ Other
出版者
言語 en
出版者 ACS Publications
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1021/acs.chemrev.9b00544
ISSN(print)
収録物識別子タイプ PISSN
収録物識別子 0009-2665
書誌情報 en : Chemical Reviews

巻 120, 号 12, p. 5194-5251, 発行日 2020-06-24
著者版フラグ
値 author
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