{"_buckets": {"deposit": "21bee5fb-5764-4cd3-9490-697cbd764665"}, "_deposit": {"id": "5452", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "5452"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00005452", "sets": ["696"]}, "author_link": ["14038", "14039", "14040", "14041", "14042"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1998-05-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "17", "bibliographicPageEnd": "7172", "bibliographicPageStart": "7161", "bibliographicVolumeNumber": "108", "bibliographic_titles": [{"bibliographic_title": "The Journal of Chemical Physics", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "O(^1D) and O(^3P_j) photofragments produced in the photodissociation of ozone in the wavelength range 305–329 nm both at 295 and 227 K have been detected directly using a technique of laser induced fluorescence (LIF) in the vacuum ultraviolet (vuv). Photofragment excitation (PHOFEX) spectra for both species have been measured by scanning the photodissociation laser wavelength whilst monitoring vuv-LIF at 115 nm [O(^1D)] and 130 nm [O(^3P_j)]. After applying suitable corrections for the relative detection sensitivities, suitably weighted combinations of these PHOFEX spectra were found to provide a quantitative match to the parent O_3 absorption spectrum both at 295 and 227 K, thereby providing a method of determining both the wavelength and temperature dependence of the absolute O(^1D) quantum yield, Φ_{1D}(λ,T). Hot band excitation of internally excited O_3 molecules and dissociation via the spin-allowed channel yielding O(^1D)+O_2(a^1Δg) products makes the dominant contribution to the quantum yield Φ_{1D}(λ T) in the wavelength range 310–320 nm. For λ\u003e320 nm, however, both the Doppler profiles of the nascent O(^1D) atoms and the temperature dependence of the O(^1D) yield indicate that the O(^1D) atoms must arise predominantly via the spin-forbidden channel yielding O(^1D)+O_2(X^3∑_g^-). The analysis allows a first determination of the absolute branching to this channel (Φ～0.08) following O_3 photolysis in the wavelength range 318–329 nm. The present work highlights remaining deficiencies in the latest NASA/JPL recommendations regarding the wavelength and temperature dependence of the O(^1D) yield resulting from O_3 photolysis at λ\u003e320 nm.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/7056"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "American Institute of Physics", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1063/1.476133", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright (1998) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0021-9606", "subitem_source_identifier_type": "PISSN"}]}, "item_10_text_14": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_text_value": "application/pdf"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Takahashi, Kenshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "14038", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Taniguchi, Nori", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "14039", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Matsumi, Yutaka", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "14040", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kawasaki, Masahiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "14041", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ashfold, Michael N. R.", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "14042", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-02-19"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "JChemPhys_108_7161.pdf", "filesize": [{"value": "270.0 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 270000.0, "url": {"label": "JChemPhys_108_7161.pdf", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/5452/files/JChemPhys_108_7161.pdf"}, "version_id": "ffb8ca2c-61d5-4ed7-a045-668c3392f1d7"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Wavelength and temperature dependence of the absolute O(^1D) production yield from the 305–329 nm photodissociation of ozone", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Wavelength and temperature dependence of the absolute O(^1D) production yield from the 305–329 nm photodissociation of ozone", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["696"], "permalink_uri": "http://hdl.handle.net/2237/7056", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2006-10-25"}, "publish_date": "2006-10-25", "publish_status": "0", "recid": "5452", "relation": {}, "relation_version_is_last": true, "title": ["Wavelength and temperature dependence of the absolute O(^1D) production yield from the 305–329 nm photodissociation of ozone"], "weko_shared_id": -1}