ログイン
言語:

WEKO3

  • トップ
  • ランキング
To
lat lon distance
To

Field does not validate



インデックスリンク

インデックスツリー

メールアドレスを入力してください。

WEKO

One fine body…

WEKO

One fine body…

アイテム

{"_buckets": {"deposit": "47737619-69ec-494a-aeb5-67a73a81ddcd"}, "_deposit": {"id": "5462", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "5462"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00005462", "sets": ["490"]}, "author_link": ["14069", "14070", "14071", "14072"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2005-06-22", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "24", "bibliographicPageEnd": "244509", "bibliographicPageStart": "244509", "bibliographicVolumeNumber": "122", "bibliographic_titles": [{"bibliographic_title": "The Journal of Chemical Physics", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Liquid methanol at densities up to ρ/ρ_0=1.7 was studied by NMR in a specially designed diamond-anvil cell. Methyl and hydroxyl resonances have been separately observed at pressures to 43 kbars which exceeds equilibrium freezing pressure of methanol. The chemical shift difference between methyl and hydroxyl protons increases nonlinearly with increasing density, indicating a noticeable decrease in hydrogen bond length. The analyses of spin-lattice relaxation rates of both hydroxyl and methyl protons indicate that compression enhances intermolecular proton exchange and selectively reduces motion of the hydroxyl protons. Collectively these observations reveal that hydrogen bonding interaction in liquid methanol noticeably increases with compression, inhibiting the liquid-solid transition even above the freezing pressure.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/7067"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "American Institute of Physics", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1063/1.1944732", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright (2005) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0021-9606", "subitem_source_identifier_type": "PISSN"}]}, "item_10_text_14": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_text_value": "application/pdf"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Okuchi, Takuo", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "14069", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Cody, George D.", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "14070", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Mao, Ho-kwang", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "14071", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hemley, Russell J.", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "14072", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-02-19"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "JChemPhys_122_244509.pdf", "filesize": [{"value": "102.5 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 102500.0, "url": {"label": "JChemPhys_122_244509.pdf", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/5462/files/JChemPhys_122_244509.pdf"}, "version_id": "05cd8ccb-37ce-4e2c-af08-35b62d1b0ab5"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Hydrogen bonding and dynamics of methanol by high-pressure diamond-anvil cell NMR", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Hydrogen bonding and dynamics of methanol by high-pressure diamond-anvil cell NMR", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["490"], "permalink_uri": "http://hdl.handle.net/2237/7067", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2006-10-25"}, "publish_date": "2006-10-25", "publish_status": "0", "recid": "5462", "relation": {}, "relation_version_is_last": true, "title": ["Hydrogen bonding and dynamics of methanol by high-pressure diamond-anvil cell NMR"], "weko_shared_id": -1}
  1. D300 大学院環境学研究科
  2. D300a 雑誌掲載論文
  3. 学術雑誌

Hydrogen bonding and dynamics of methanol by high-pressure diamond-anvil cell NMR

http://hdl.handle.net/2237/7067
http://hdl.handle.net/2237/7067
bcaddcea-0a02-4f6f-8460-532fb2fc0144
名前 / ファイル ライセンス アクション
JChemPhys_122_244509.pdf JChemPhys_122_244509.pdf (102.5 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2006-10-25
タイトル
タイトル Hydrogen bonding and dynamics of methanol by high-pressure diamond-anvil cell NMR
言語 en
著者 Okuchi, Takuo

× Okuchi, Takuo

WEKO 14069

en Okuchi, Takuo

Search repository
Cody, George D.

× Cody, George D.

WEKO 14070

en Cody, George D.

Search repository
Mao, Ho-kwang

× Mao, Ho-kwang

WEKO 14071

en Mao, Ho-kwang

Search repository
Hemley, Russell J.

× Hemley, Russell J.

WEKO 14072

en Hemley, Russell J.

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 Copyright (2005) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.
抄録
内容記述 Liquid methanol at densities up to ρ/ρ_0=1.7 was studied by NMR in a specially designed diamond-anvil cell. Methyl and hydroxyl resonances have been separately observed at pressures to 43 kbars which exceeds equilibrium freezing pressure of methanol. The chemical shift difference between methyl and hydroxyl protons increases nonlinearly with increasing density, indicating a noticeable decrease in hydrogen bond length. The analyses of spin-lattice relaxation rates of both hydroxyl and methyl protons indicate that compression enhances intermolecular proton exchange and selectively reduces motion of the hydroxyl protons. Collectively these observations reveal that hydrogen bonding interaction in liquid methanol noticeably increases with compression, inhibiting the liquid-solid transition even above the freezing pressure.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 American Institute of Physics
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1063/1.1944732
ISSN
収録物識別子タイプ PISSN
収録物識別子 0021-9606
書誌情報 en : The Journal of Chemical Physics

巻 122, 号 24, p. 244509-244509, 発行日 2005-06-22
フォーマット
application/pdf
著者版フラグ
値 publisher
URI
識別子 http://hdl.handle.net/2237/7067
識別子タイプ HDL
戻る
0
views
See details
Views

Versions

Ver.1 2021-03-01 13:10:43.435109
Show All versions

Share

Mendeley Twitter Facebook Print Addthis

Cite as

エクスポート

OAI-PMH
  • OAI-PMH JPCOAR
  • OAI-PMH DublinCore
  • OAI-PMH DDI
Other Formats
  • JSON
  • BIBTEX

Confirm


Powered by WEKO3


Powered by WEKO3