{"_buckets": {"deposit": "d6591d7e-5532-49ee-912e-f46a04c821a8"}, "_deposit": {"id": "7679", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "7679"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00007679"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2007", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "350", "bibliographicPageStart": "347", "bibliographicVolumeNumber": "156-158", "bibliographic_titles": [{"bibliographic_title": "Journal of Electron Spectroscopy and Related Phenomena"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The valence-band electronic structures of the Heusler-type alloys Fe_2VAl_1-zGe_z (z = 0 - 0.10) have been investigated with high-resolution soft x-ray photoemission spectroscopy. The overall photoelectron spectral feature of Fe_2VAl_1-zGe_z with the Ge content z up to 0.10 is not so much changed, except for the main 3d band in the region from the Fermi level E_F to the binding energy E_B\u22451 eV. For z = 0.05, the leading edge of the main band is shifted by ~ 0.07 eV, but the shift is much smaller than expected within a rigid band model for a calculated band structure. For z = 0.10, a band at E_B\u2245 0.5 eV becomes prominent and the intensity of the Fermi edge is increased. The change in the valence band spectrum near E_F suggests the rigid-band-like shift of the 3d bands and the appearance of new 3d states in the pseudogap, which may qualitatively explain the z-dependence of the thermoelectric properties. As z increases, the V 2p spectra show a shift towards the high binding energy and the evolution of a shoulder structure on the low binding energy side of the main line. The shoulder structure is attributed to the charge transfer to the V site induced by the Ge substitution as well as the surface effect. The change in the valence-band electronic structure is discussed in terms of the interaction between the substituted Ge and its surrounding constituent atoms.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/9386"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Elsevier"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1016/j.elspec.2007.01.001", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "This is the author\u2019s version of a work accepted for publication by Elsevier. Changes resulting from the publishing process, including peer review, editing, corrections, structural formatting and other quality control mechanisms, may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Electron Spectroscopy and Related Phenomena. v.156-158, 2007, http://dx.doi.org/10.1016/j.elspec.2007.01.001"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "03682048", "subitem_source_identifier_type": "ISSN"}]}, "item_10_text_14": {"attribute_name": "\u30d5\u30a9\u30fc\u30de\u30c3\u30c8", "attribute_value_mlt": [{"subitem_text_value": "application/pdf"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "MIYAZAKI, Hidetoshi"}], "nameIdentifiers": [{"nameIdentifier": "21780", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "SODA, Kazuo"}], "nameIdentifiers": [{"nameIdentifier": "21781", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "KATO, Masahiko"}], "nameIdentifiers": [{"nameIdentifier": "21782", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "YAGI, Shinya"}], "nameIdentifiers": [{"nameIdentifier": "21783", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-02-19"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "procICESS10_061019.pdf", "filesize": [{"value": "204.4 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 204400.0, "url": {"label": "procICESS10_061019.pdf", "url": "https://nagoya.repo.nii.ac.jp/record/7679/files/procICESS10_061019.pdf"}, "version_id": "57c4023a-2cf3-4b80-83a1-40563a213417"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Soft X-ray photoemission spectroscopy", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Valence band electronic structure", "subitem_subject_scheme": "Other"}, {"subitem_subject": "V 2p core level", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Fe_2VAl_1\u2212zGe_z", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Heusler-type alloys", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Thermoelectric properties", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Soft x-ray photoemission study of the Heusler-type Fe_2VAl_1-zGe_z alloys", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Soft x-ray photoemission study of the Heusler-type Fe_2VAl_1-zGe_z alloys"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/9386", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2008-01-29"}, "publish_date": "2008-01-29", "publish_status": "0", "recid": "7679", "relation": {}, "relation_version_is_last": true, "title": ["Soft x-ray photoemission study of the Heusler-type Fe_2VAl_1-zGe_z alloys"], "weko_shared_id": 3}