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Appearance of a homochiral state of crystals induced by random fluctuation in grinding
http://hdl.handle.net/2237/20571
http://hdl.handle.net/2237/20571277e743a-01f1-4eb3-a970-f9d3f36137f3
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
PhysRevE_86_051608.pdf (347.6 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2014-09-26 | |||||
| タイトル | ||||||
| タイトル | Appearance of a homochiral state of crystals induced by random fluctuation in grinding | |||||
| 言語 | en | |||||
| 著者 |
Katsuno, Hiroyasu
× Katsuno, Hiroyasu× Uwaha, Makio |
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| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 権利 | ||||||
| 言語 | en | |||||
| 権利情報 | ©2012 American Physical Society | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | We study crystallization of chiral crystals from achiral molecules using a master equation based on a simple reaction model. Although there is no chiral symmetry breaking in the reaction model, random fluctuations drive the system to a homochiral state. The time necessary for the appearance of the homochiral state is proportional to the total number of molecules in the system. This behavior is described by a diffusion equation in a size space with a position-dependent diffusion coefficient. We also study the effect of chiral impurities, which affect the crystal growth. Depending on the type of impurities, the chiral symmetry breaking occurs either deterministically or with the help of random fluctuations. | |||||
| 言語 | en | |||||
| 出版者 | ||||||
| 出版者 | American Physical Society | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | journal article | |||||
| 出版タイプ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1103/PhysRevE.86.051608 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 1539-3755 | |||||
| 書誌情報 |
en : Physical Review E 巻 86, p. 051608-051608, 発行日 2012-11-19 |
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| 著者版フラグ | ||||||
| 値 | publisher | |||||
| URI | ||||||
| 識別子 | http://dx.doi.org/10.1103/PhysRevE.86.051608 | |||||
| 識別子タイプ | DOI | |||||
| URI | ||||||
| 識別子 | http://hdl.handle.net/2237/20571 | |||||
| 識別子タイプ | HDL | |||||
