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  1. D400 創薬科学研究科
  2. D400a 雑誌掲載論文
  3. 学術雑誌

Total Synthesis of Haliclonin A

http://hdl.handle.net/2237/0002001506
http://hdl.handle.net/2237/0002001506
04895b73-2d8e-40e4-b557-5e2102774bf6
名前 / ファイル ライセンス アクション
20210203_jin.pdf 20210203_jin.pdf (1.1 MB)
Item type itemtype_ver1(1)
公開日 2021-10-13
タイトル
タイトル Total Synthesis of Haliclonin A
言語 en
著者 Jin, Yuan

× Jin, Yuan

en Jin, Yuan

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Orihara, Kensuke

× Orihara, Kensuke

en Orihara, Kensuke

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Kawagishi, Fumiki

× Kawagishi, Fumiki

en Kawagishi, Fumiki

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Toma, Tatsuya

× Toma, Tatsuya

en Toma, Tatsuya

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Fukuyama, Tohru

× Fukuyama, Tohru

en Fukuyama, Tohru

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Yokoshima, Satoshi

× Yokoshima, Satoshi

en Yokoshima, Satoshi

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アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 "This is the peer reviewed version of the following article: [Y. Jin, K. Orihara, F. Kawagishi, T. Toma, T. Fukuyama, S. Yokoshima, Angew. Chem. Int. Ed. 2021, 60, 9666.], which has been published in final form at [https://doi.org/10.1002/anie.202016343]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited."
内容記述
内容記述 The total synthesis of haliclonin A was accomplished. Starting from 3,5-dimethoxybenzoic acid, a functionalized cyclohexanone fused to a 17-membered ring was prepared through a Birch reduction/alkylation sequence, ring-closing metathesis, intramolecular cyclopropanation, and stereoselective 1,4-addition of an organocopper reagent to an enone moiety. Reductive C−N bond formation via an N,O-acetal forged the 3-azabicyclo[3.3.1]nonane core. The allyl alcohol moiety was constructed by a sequence involving stereoselective α-selenylation of an aldehyde via an enamine, syn-elimination of a selenoxide, and allylation of the aldehyde with an allylboronate. Formation of the 15-membered ring containing a skipped diene was achieved by ring-closing metathesis, and final transformations led to the synthesis of haliclonin A.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
関連情報
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/anie.202016343
収録物識別子
収録物識別子タイプ PISSN
収録物識別子 1433-7851
書誌情報 en : Angewandte Chemie International Edition

巻 60, 号 17, p. 9666-9671, 発行日 2021-04-19
ファイル公開日
日付 2022-04-19
日付タイプ Available
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