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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Exploring Cu-Based Spinel/Delafossite Couples for Thermochemical Energy Storage at Medium-High Temperature

http://hdl.handle.net/2237/0002002104
http://hdl.handle.net/2237/0002002104
fa64886f-7e57-4148-a29e-8134303d9f1c
名前 / ファイル ライセンス アクション
Chen-AppliedEnergyMaterials-21.pdf Chen-AppliedEnergyMaterials-21.pdf (3.4 MB)
Item type itemtype_ver1(1)
公開日 2022-02-18
タイトル
タイトル Exploring Cu-Based Spinel/Delafossite Couples for Thermochemical Energy Storage at Medium-High Temperature
言語 en
著者 Chen, Xiaoyu

× Chen, Xiaoyu

en Chen, Xiaoyu

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Kubota, Mitsuhiro

× Kubota, Mitsuhiro

en Kubota, Mitsuhiro

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Yamashita, Seiji

× Yamashita, Seiji

en Yamashita, Seiji

Search repository
Kita, Hideki

× Kita, Hideki

en Kita, Hideki

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Organic Chemistry], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-AI8V9IUEK6EKACDNGCWI].”
キーワード
主題Scheme Other
主題 heat storage
キーワード
主題Scheme Other
主題 TCES
キーワード
主題Scheme Other
主題 medium-high temperature
キーワード
主題Scheme Other
主題 Cu-based oxides
キーワード
主題Scheme Other
主題 spinels
キーワード
主題Scheme Other
主題 delafossites
内容記述
内容記述 Cu-based spinel/delafossite couples with Mn and Fe as second cations were synthesized using the Pechini method for medium-high temperature thermochemical energy storage. Physicochemical properties of each sample were investigated. Only CuMn2O4/CuMnO2 exhibited favorable redox behavior in the range of 500–1000 °C. Cu-based delafossite can reoxidize at a lower temperature (∼600 °C), which may be related to the existence of a MO6 octahedra structure. Through the isothermal oxidation method, CuMn2O4/CuMnO2 couple showed a larger oxidation enthalpy of 258.32 ± 15.31 kJ/kg (1402.68 ± 83.13 kJ/L) than 190.35 ± 4.81 kJ/kg (1048.83 ± 26.50 kJ/L) of CuFe2O4/CuFeO2 couple. CuMn2O4 was chosen for further cyclability test with 20 cycles; the depth of reduction increased gradually and stabilized at 4% change in mass after 13 cycles.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 ACS Publications
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
関連情報
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1021/acsaem.1c01352
収録物識別子
収録物識別子タイプ EISSN
収録物識別子 2574-0962
書誌情報 en : ACS Applied Energy Materials

巻 4, 号 7, p. 7242-7249, 発行日 2021-07-26
ファイル公開日
日付 2022-07-26
日付タイプ Available
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