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Mechanism of chirality conversion by periodic change of temperature: Role of chiral clusters
http://hdl.handle.net/2237/23425
http://hdl.handle.net/2237/23425faf617ea-419c-4375-9f47-e0cea72a7cac
名前 / ファイル | ライセンス | アクション |
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tempcycle_151210_submit.pdf (238.7 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2016-01-25 | |||||
タイトル | ||||||
タイトル | Mechanism of chirality conversion by periodic change of temperature: Role of chiral clusters | |||||
言語 | en | |||||
著者 |
Katsuno, Hiroyasu
× Katsuno, Hiroyasu× Uwaha, Makio |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | ©2016 American Physical Society | |||||
抄録 | ||||||
内容記述 | By grinding crystals in a solution, the chirality of crystal structure (and the molecular chirality for the case of chiral molecules as well) can be converted, and the cause of the phenomenon is attributed to crystal growth with chiral clusters. We show that the recently found chirality conversion with a periodic change of temperature can also be explained by crystal growth with chiral clusters. With the use of a generalized Becker-Döring model, which includes enantio-selective incorporation of small chiral clusters to large solid clusters, the change of cluster distribution and the mass flow between clusters are studied. The chiral clusters act as a reservoir to pump out the minority species to the majority, and the exponential amplification of the enantiomeric excess found in the experiment is reproduced in the numerical calculation. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | American Physical Society | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1103/PhysRevE.93.013002 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1539-3755 | |||||
書誌情報 |
en : Physical Review E 巻 93, p. 013002-013002, 発行日 2016-01 |
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著者版フラグ | ||||||
値 | author | |||||
URI | ||||||
識別子 | http://dx.doi.org/10.1103/PhysRevE.93.013002 | |||||
識別子タイプ | DOI | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/23425 | |||||
識別子タイプ | HDL |