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  1. B100 理学部/理学研究科
  2. B100a 雑誌掲載論文
  3. 学術雑誌

Mechanism of chirality conversion by periodic change of temperature: Role of chiral clusters

http://hdl.handle.net/2237/23425
http://hdl.handle.net/2237/23425
faf617ea-419c-4375-9f47-e0cea72a7cac
名前 / ファイル ライセンス アクション
tempcycle_151210_submit.pdf tempcycle_151210_submit.pdf (238.7 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2016-01-25
タイトル
タイトル Mechanism of chirality conversion by periodic change of temperature: Role of chiral clusters
言語 en
著者 Katsuno, Hiroyasu

× Katsuno, Hiroyasu

WEKO 61392

en Katsuno, Hiroyasu

Search repository
Uwaha, Makio

× Uwaha, Makio

WEKO 61393

en Uwaha, Makio

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 ©2016 American Physical Society
抄録
内容記述 By grinding crystals in a solution, the chirality of crystal structure (and the molecular chirality for the case of chiral molecules as well) can be converted, and the cause of the phenomenon is attributed to crystal growth with chiral clusters. We show that the recently found chirality conversion with a periodic change of temperature can also be explained by crystal growth with chiral clusters. With the use of a generalized Becker-Döring model, which includes enantio-selective incorporation of small chiral clusters to large solid clusters, the change of cluster distribution and the mass flow between clusters are studied. The chiral clusters act as a reservoir to pump out the minority species to the majority, and the exponential amplification of the enantiomeric excess found in the experiment is reproduced in the numerical calculation.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 American Physical Society
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1103/PhysRevE.93.013002
ISSN
収録物識別子タイプ PISSN
収録物識別子 1539-3755
書誌情報 en : Physical Review E

巻 93, p. 013002-013002, 発行日 2016-01
著者版フラグ
値 author
URI
識別子 http://dx.doi.org/10.1103/PhysRevE.93.013002
識別子タイプ DOI
URI
識別子 http://hdl.handle.net/2237/23425
識別子タイプ HDL
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