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  1. D400 創薬科学研究科
  2. D400a 雑誌掲載論文
  3. 学術雑誌

Total Synthesis of (−)-Daphenylline

http://hdl.handle.net/2237/25060
http://hdl.handle.net/2237/25060
2c7c0148-b903-4f38-b8df-9f074d13be1e
名前 / ファイル ライセンス アクション
20160318_daphenylline.pdf 20160318_daphenylline.pdf ファイル公開:2017-05-10 (1.0 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2016-11-18
タイトル
タイトル Total Synthesis of (−)-Daphenylline
言語 en
著者 Yamada, Ryosuke

× Yamada, Ryosuke

WEKO 67333

en Yamada, Ryosuke

Search repository
Adachi, Yohei

× Adachi, Yohei

WEKO 67334

en Adachi, Yohei

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Yokoshima, Satoshi

× Yokoshima, Satoshi

WEKO 67335

en Yokoshima, Satoshi

Search repository
Fukuyama, Tohru

× Fukuyama, Tohru

WEKO 67336

en Fukuyama, Tohru

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This is the peer reviewed version of the following article: [ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. v.55, n.20, 2016, p.6067-6070], which has been published in final form at [http://doi.org/10.1002/anie.201601958]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
抄録
内容記述 Total synthesis of (−)-daphenylline, a hexacyclic Daphniphyllum alkaloid, was achieved. Construction of the tricyclic DEF ring system was initiated by asymmetric Negishi coupling followed by an intramolecular Friedel–Crafts reaction. Installation of a side chain onto the tricyclic core was carried out through Sonogashira coupling, stereocontrolled Claisen rearrangement by taking advantage of the characteristic conformation of the tricyclic DEF core, and the stereoselective alkylation of a lactone. After the introduction of a glycine unit, the ABC ring system was stereoselectively constructed through intramolecular cycloaddition of the cyclic azomethine ylide.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/anie.201601958
ISSN
収録物識別子タイプ PISSN
収録物識別子 1433-7851
書誌情報 en : ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

巻 55, 号 20, p. 6067-6070, 発行日 2016-05-10
著者版フラグ
値 author
URI
識別子 http://doi.org/10.1002/anie.201601958
識別子タイプ DOI
URI
識別子 http://hdl.handle.net/2237/25060
識別子タイプ HDL
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