{"_buckets": {"deposit": "89484244-ef09-4638-9a0a-ccf7b459fca1"}, "_deposit": {"id": "22905", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "22905"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00022905"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2016-06-03", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "12", "bibliographicPageEnd": "2981", "bibliographicPageStart": "2978", "bibliographicVolumeNumber": "18", "bibliographic_titles": [{"bibliographic_title": "Organic Letters"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A novel synthetic protocol has been developed for free-base 10-azacorroles. Ni(0)-mediated homocoupling of nitrogen-bridged bisdipyrrin Zn(II) complexes afforded a series of free-base 5,15-diaryl-10-azacorroles in good yields. Pd(II) and Cu(II) complexes have been prepared through metalation of free-base 10-azacorroles. Optical and electrochemical properties of 10-azacorrole metal complexes can be tuned by meso-aryl substituents and central metals. Cyclic voltammetry and theoretical calculations elucidated that the central metals of 10-azacorroles significantly affected their electronic properties.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://doi.org/10.1021/acs.orglett.6b01323"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/25083"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications"}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u201cThis document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-JDsEtKFiQ9Zwi8sGKbHQ].\u201d"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1523-7060", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Omori, Hiroto"}], "nameIdentifiers": [{"nameIdentifier": "67404", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hiroto, Satoru"}], "nameIdentifiers": [{"nameIdentifier": "67405", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shinokubo, Hiroshi"}], "nameIdentifiers": [{"nameIdentifier": "67406", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-06-03"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "ol-2016-01323x.pdf", "filesize": [{"value": "1.3 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1300000.0, "url": {"label": "ol-2016-01323x.pdf \u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2017-06-03", "url": "https://nagoya.repo.nii.ac.jp/record/22905/files/ol-2016-01323x.pdf"}, "version_id": "2aadeae3-f09f-436e-aa38-9accc39f807c"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of Free-Base 10-Azacorroles", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Synthesis of Free-Base 10-Azacorroles"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/25083", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2016-11-22"}, "publish_date": "2016-11-22", "publish_status": "0", "recid": "22905", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of Free-Base 10-Azacorroles"], "weko_shared_id": null}