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Synthesis of Free-Base 10-Azacorroles
http://hdl.handle.net/2237/25083
ec28c55b-0e73-4bdd-a6b4-ef044d494961
名前 / ファイル | ライセンス | アクション | |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2016-11-22 | |||||
タイトル | ||||||
タイトル | Synthesis of Free-Base 10-Azacorroles | |||||
著者 |
Omori, Hiroto
× Omori, Hiroto× Hiroto, Satoru× Shinokubo, Hiroshi |
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権利 | ||||||
権利情報 | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-JDsEtKFiQ9Zwi8sGKbHQ].” | |||||
抄録 | ||||||
内容記述 | A novel synthetic protocol has been developed for free-base 10-azacorroles. Ni(0)-mediated homocoupling of nitrogen-bridged bisdipyrrin Zn(II) complexes afforded a series of free-base 5,15-diaryl-10-azacorroles in good yields. Pd(II) and Cu(II) complexes have been prepared through metalation of free-base 10-azacorroles. Optical and electrochemical properties of 10-azacorrole metal complexes can be tuned by meso-aryl substituents and central metals. Cyclic voltammetry and theoretical calculations elucidated that the central metals of 10-azacorroles significantly affected their electronic properties. | |||||
内容記述タイプ | Abstract | |||||
出版者 | ||||||
出版者 | ACS Publications | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1523-7060 | |||||
書誌情報 |
Organic Letters 巻 18, 号 12, p. 2978-2981, 発行日 2016-06-03 |
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著者版フラグ | ||||||
値 | author | |||||
URI | ||||||
識別子 | http://doi.org/10.1021/acs.orglett.6b01323 | |||||
識別子タイプ | DOI | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/25083 | |||||
識別子タイプ | HDL |