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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Highly Extensible Supramolecular Elastomers with Large Stress Generation Capability Originating from Multiple Hydrogen Bonds on the Long Soft Network Strands

http://hdl.handle.net/2237/25168
http://hdl.handle.net/2237/25168
7db600a0-129b-461d-b6c1-d8e185c68f0e
名前 / ファイル ライセンス アクション
manuscript.pdf manuscript.pdf ファイル公開:2017/04/20 (877.3 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2016-12-08
タイトル
タイトル Highly Extensible Supramolecular Elastomers with Large Stress Generation Capability Originating from Multiple Hydrogen Bonds on the Long Soft Network Strands
言語 en
著者 Hayashi, Mikihiro

× Hayashi, Mikihiro

WEKO 67882

en Hayashi, Mikihiro

Search repository
Noro, Atsushi

× Noro, Atsushi

WEKO 67883

en Noro, Atsushi

Search repository
Matsushita, Yushu

× Matsushita, Yushu

WEKO 67884

en Matsushita, Yushu

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This is the peer reviewed version of the following article: [Hayashi, M., Noro, A. and Matsushita, Y. (2016), Highly Extensible Supramolecular Elastomers with Large Stress Generation Capability Originating from Multiple Hydrogen Bonds on the Long Soft Network Strands. Macromol. Rapid Commun., 37: 678–684], which has been published in final form at [http://doi.org/10.1002/marc.201500663]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
キーワード
主題Scheme Other
主題 ABA triblock copolymers
キーワード
主題Scheme Other
主題 high extensibility
キーワード
主題Scheme Other
主題 high-pressure RAFT polymerization
キーワード
主題Scheme Other
主題 large stress generation capability
キーワード
主題Scheme Other
主題 supramolecular elastomers
抄録
内容記述 Highly extensible supramolecular elastomers are prepared from ABA triblock-type copolymers bearing glassy end blocks and a long soft middle block with multiple hydrogen bonds. The copolymer used is polystyrene-b-[poly(butyl acrylate)-co-polyacrylamide]-b-polystyrene (S-Ba-S), which is synthesized via reversible addition–fragmentation chain transfer (RAFT) polymerization. Tensile tests reveal that the breaking elongation (εb) increases with an increase in the middle block molecular weight (Mmiddle). Especially, the largest S-Ba-S with Mmiddle of 3140k, which is synthesized via high-pressure RAFT polymerization, achieves εb of over 2000% with a maximum tensile stress of 3.6 MPa, while the control sample without any middle block hydrogen bonds, polystyrene-b-poly(butyl acrylate)-b-polystyrene with Mmiddle of 2780k, is merely a viscous material due to the large volume fraction of soft block. Thus, incorporation of hydrogen bonds into the large molecular weight soft middle block is found to be beneficial to prepare supramolecular elastomers attaining high extensibility and sufficiently large stress generation ability simultaneously. This outcome is probably due to concerted combination of entropic changes and internal potential energy changes originating from the dissociation of multiple hydrogen bonds by elongation.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/marc.201500663
ISSN
収録物識別子タイプ PISSN
収録物識別子 1022-1336
書誌情報 en : MACROMOLECULAR RAPID COMMUNICATIONS

巻 37, 号 8, p. 678-684, 発行日 2016-04
著者版フラグ
値 author
URI
識別子 http://doi.org/10.1002/marc.201500663
識別子タイプ DOI
URI
識別子 http://hdl.handle.net/2237/25168
識別子タイプ HDL
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