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Highly Extensible Supramolecular Elastomers with Large Stress Generation Capability Originating from Multiple Hydrogen Bonds on the Long Soft Network Strands
http://hdl.handle.net/2237/25168
http://hdl.handle.net/2237/251687db600a0-129b-461d-b6c1-d8e185c68f0e
名前 / ファイル | ライセンス | アクション |
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manuscript.pdf ファイル公開:2017/04/20 (877.3 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2016-12-08 | |||||
タイトル | ||||||
タイトル | Highly Extensible Supramolecular Elastomers with Large Stress Generation Capability Originating from Multiple Hydrogen Bonds on the Long Soft Network Strands | |||||
言語 | en | |||||
著者 |
Hayashi, Mikihiro
× Hayashi, Mikihiro× Noro, Atsushi× Matsushita, Yushu |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | This is the peer reviewed version of the following article: [Hayashi, M., Noro, A. and Matsushita, Y. (2016), Highly Extensible Supramolecular Elastomers with Large Stress Generation Capability Originating from Multiple Hydrogen Bonds on the Long Soft Network Strands. Macromol. Rapid Commun., 37: 678–684], which has been published in final form at [http://doi.org/10.1002/marc.201500663]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | ABA triblock copolymers | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | high extensibility | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | high-pressure RAFT polymerization | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | large stress generation capability | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | supramolecular elastomers | |||||
抄録 | ||||||
内容記述 | Highly extensible supramolecular elastomers are prepared from ABA triblock-type copolymers bearing glassy end blocks and a long soft middle block with multiple hydrogen bonds. The copolymer used is polystyrene-b-[poly(butyl acrylate)-co-polyacrylamide]-b-polystyrene (S-Ba-S), which is synthesized via reversible addition–fragmentation chain transfer (RAFT) polymerization. Tensile tests reveal that the breaking elongation (εb) increases with an increase in the middle block molecular weight (Mmiddle). Especially, the largest S-Ba-S with Mmiddle of 3140k, which is synthesized via high-pressure RAFT polymerization, achieves εb of over 2000% with a maximum tensile stress of 3.6 MPa, while the control sample without any middle block hydrogen bonds, polystyrene-b-poly(butyl acrylate)-b-polystyrene with Mmiddle of 2780k, is merely a viscous material due to the large volume fraction of soft block. Thus, incorporation of hydrogen bonds into the large molecular weight soft middle block is found to be beneficial to prepare supramolecular elastomers attaining high extensibility and sufficiently large stress generation ability simultaneously. This outcome is probably due to concerted combination of entropic changes and internal potential energy changes originating from the dissociation of multiple hydrogen bonds by elongation. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Wiley | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/marc.201500663 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1022-1336 | |||||
書誌情報 |
en : MACROMOLECULAR RAPID COMMUNICATIONS 巻 37, 号 8, p. 678-684, 発行日 2016-04 |
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著者版フラグ | ||||||
値 | author | |||||
URI | ||||||
識別子 | http://doi.org/10.1002/marc.201500663 | |||||
識別子タイプ | DOI | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/25168 | |||||
識別子タイプ | HDL |