{"_buckets": {"deposit": "cddc9e21-d2fd-4e84-ad4b-42e9ce502cbe"}, "_deposit": {"id": "23049", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "23049"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00023049", "sets": ["1941"]}, "author_link": ["68182", "68183", "68184"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2016-12", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "412", "bibliographicPageStart": "404", "bibliographicVolumeNumber": "688B", "bibliographic_titles": [{"bibliographic_title": "Journal of Alloys and Compounds", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The dynamics of hydrogen-induced vacancies are the key for understanding various phenomena in metal–hydrogen systems under a high hydrogen chemical potential. In this study, a novel dry-electrolysis experiment was performed in which a hydrogen isotope was injected into a Pd cathode and time-resolved in situ monochromatic X-ray diffraction measurement was carried out at the Pd cathode. It was found that palladium-hydride containing vacancies forms multiple phases depending on the hydrogen chemical potential. Phase separation into vacancy-rich, vacancy-poor, and moderate-vacancy-concentration phases was observed when the input voltage was relatively low, i.e., ∼0.5 V. The moderate-vacancy-concentration phase may be attributed to Ca7Ge or another type of super-lattice Pd7VacH(D)8. Transition from the vacancy-rich to the moderate-vacancy-concentration phase explains the sub-micron void formations without high temperature treatment that were observed at the Pd cathode but have never been reported in previous anvil experiments.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://dx.doi.org/10.1016/j.jallcom.2016.07.176"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/25240"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Elsevier", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1016/j.jallcom.2016.07.176", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "© 2016. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0925-8388", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Fukada, Yoshiki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "68182", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hioki, Tatsumi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "68183", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Motohiro, Tomoyoshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "68184", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-12-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "sav2_paper_riv_submit.pdf", "filesize": [{"value": "2.7 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 2700000.0, "url": {"label": "sav2_paper_riv_submit.pdf ファイル公開：2018/12/01", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/23049/files/sav2_paper_riv_submit.pdf"}, "version_id": "f48956d9-e234-4c8f-bb44-ae4689c833b4"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Multiple phase separation of super-abundant-vacancies in Pd hydrides by all solid-state electrolysis in moderate temperatures around 300 °C", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Multiple phase separation of super-abundant-vacancies in Pd hydrides by all solid-state electrolysis in moderate temperatures around 300 °C", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["1941"], "permalink_uri": "http://hdl.handle.net/2237/25240", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2016-12-16"}, "publish_date": "2016-12-16", "publish_status": "0", "recid": "23049", "relation": {}, "relation_version_is_last": true, "title": ["Multiple phase separation of super-abundant-vacancies in Pd hydrides by all solid-state electrolysis in moderate temperatures around 300 °C"], "weko_shared_id": -1}