{"_buckets": {"deposit": "8396c2b3-8111-4076-a67b-5eb811833481"}, "_deposit": {"id": "23206", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "23206"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00023206"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2016-04", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "7", "bibliographicPageEnd": "1067", "bibliographicPageStart": "1061", "bibliographicVolumeNumber": "27", "bibliographic_titles": [{"bibliographic_title": "Synlett"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Chiral supramolecular boron Lewis acid catalysts were prepared from chiral 3-phosphoryl-1,1\u2032-bi-2-naphthols, (2-cyanophenyl)boronic acids, and tris(pentafluorophenyl)borane, bound through CN\u00b7\u00b7\u00b7B and PO\u00b7\u00b7\u00b7B coordination bonds. In particular, the coordinated tris(pentafluorophenyl)boranes increase the Lewis acidity of the active center in the manner of a Lewis acid assisted Lewis acid catalyst system. A possible cavity in these catalysts was highly suitable for several Diels\u2013Alder probe reactions of acroleins with cyclic or acyclic dienes, which gave the corresponding adducts in good to high yields and high enantio\u00adselectivities.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://doi.org/10.1055/s-0035-1561362"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/25400"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Georg Thieme Verlag"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0936-5214", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hatano, Manabu"}], "nameIdentifiers": [{"nameIdentifier": "68754", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hayashi, Kazushi"}], "nameIdentifiers": [{"nameIdentifier": "68755", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakamoto, Tatsuhiro"}], "nameIdentifiers": [{"nameIdentifier": "68756", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Makino, Yuma"}], "nameIdentifiers": [{"nameIdentifier": "68757", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishihara, Kazuaki"}], "nameIdentifiers": [{"nameIdentifier": "68758", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-04-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Manuscript-revised.pdf", "filesize": [{"value": "958.3 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 958300.0, "url": {"label": "Manuscript-revised.pdf \u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2017/04/01", "url": "https://nagoya.repo.nii.ac.jp/record/23206/files/Manuscript-revised.pdf"}, "version_id": "011ed93b-c5fb-439e-a578-c4531cbbbfc8"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "supramolecular catalysts", "subitem_subject_scheme": "Other"}, {"subitem_subject": "asymmetric catalysis", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Diels\u2013Alder reactions", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Lewis acids", "subitem_subject_scheme": "Other"}, {"subitem_subject": "dienes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "aldehydes", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Enantioselective Diels\u2013Alder Reaction Induced by Chiral Supramolecular Lewis Acid Catalysts Based on CN\u00b7\u00b7\u00b7B and PO\u00b7\u00b7\u00b7B Coordination Bonds", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Enantioselective Diels\u2013Alder Reaction Induced by Chiral Supramolecular Lewis Acid Catalysts Based on CN\u00b7\u00b7\u00b7B and PO\u00b7\u00b7\u00b7B Coordination Bonds"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/25400", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2017-01-17"}, "publish_date": "2017-01-17", "publish_status": "0", "recid": "23206", "relation": {}, "relation_version_is_last": true, "title": ["Enantioselective Diels\u2013Alder Reaction Induced by Chiral Supramolecular Lewis Acid Catalysts Based on CN\u00b7\u00b7\u00b7B and PO\u00b7\u00b7\u00b7B Coordination Bonds"], "weko_shared_id": null}