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Enantioselective Diels–Alder Reaction Induced by Chiral Supramolecular Lewis Acid Catalysts Based on CN···B and PO···B Coordination Bonds
http://hdl.handle.net/2237/25400
http://hdl.handle.net/2237/25400aaa65de8-53b1-4718-834d-d6a2539127ef
名前 / ファイル | ライセンス | アクション |
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Manuscript-revised.pdf ファイル公開:2017/04/01 (958.3 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-01-17 | |||||
タイトル | ||||||
タイトル | Enantioselective Diels–Alder Reaction Induced by Chiral Supramolecular Lewis Acid Catalysts Based on CN···B and PO···B Coordination Bonds | |||||
言語 | en | |||||
著者 |
Hatano, Manabu
× Hatano, Manabu× Hayashi, Kazushi× Sakamoto, Tatsuhiro× Makino, Yuma× Ishihara, Kazuaki |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | supramolecular catalysts | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | asymmetric catalysis | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Diels–Alder reactions | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Lewis acids | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | dienes | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | aldehydes | |||||
抄録 | ||||||
内容記述 | Chiral supramolecular boron Lewis acid catalysts were prepared from chiral 3-phosphoryl-1,1′-bi-2-naphthols, (2-cyanophenyl)boronic acids, and tris(pentafluorophenyl)borane, bound through CN···B and PO···B coordination bonds. In particular, the coordinated tris(pentafluorophenyl)boranes increase the Lewis acidity of the active center in the manner of a Lewis acid assisted Lewis acid catalyst system. A possible cavity in these catalysts was highly suitable for several Diels–Alder probe reactions of acroleins with cyclic or acyclic dienes, which gave the corresponding adducts in good to high yields and high enantioselectivities. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Georg Thieme Verlag | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1055/s-0035-1561362 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 0936-5214 | |||||
書誌情報 |
en : Synlett 巻 27, 号 7, p. 1061-1067, 発行日 2016-04 |
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著者版フラグ | ||||||
値 | author | |||||
URI | ||||||
識別子 | http://doi.org/10.1055/s-0035-1561362 | |||||
識別子タイプ | DOI | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/25400 | |||||
識別子タイプ | HDL |