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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Enantioselective Diels–Alder Reaction Induced by Chiral Supramolecular Lewis Acid Catalysts Based on CN···B and PO···B Coordination Bonds

http://hdl.handle.net/2237/25400
http://hdl.handle.net/2237/25400
aaa65de8-53b1-4718-834d-d6a2539127ef
名前 / ファイル ライセンス アクション
Manuscript-revised.pdf Manuscript-revised.pdf ファイル公開:2017/04/01 (958.3 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2017-01-17
タイトル
タイトル Enantioselective Diels–Alder Reaction Induced by Chiral Supramolecular Lewis Acid Catalysts Based on CN···B and PO···B Coordination Bonds
言語 en
著者 Hatano, Manabu

× Hatano, Manabu

WEKO 68754

en Hatano, Manabu

Search repository
Hayashi, Kazushi

× Hayashi, Kazushi

WEKO 68755

en Hayashi, Kazushi

Search repository
Sakamoto, Tatsuhiro

× Sakamoto, Tatsuhiro

WEKO 68756

en Sakamoto, Tatsuhiro

Search repository
Makino, Yuma

× Makino, Yuma

WEKO 68757

en Makino, Yuma

Search repository
Ishihara, Kazuaki

× Ishihara, Kazuaki

WEKO 68758

en Ishihara, Kazuaki

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
キーワード
主題Scheme Other
主題 supramolecular catalysts
キーワード
主題Scheme Other
主題 asymmetric catalysis
キーワード
主題Scheme Other
主題 Diels–Alder reactions
キーワード
主題Scheme Other
主題 Lewis acids
キーワード
主題Scheme Other
主題 dienes
キーワード
主題Scheme Other
主題 aldehydes
抄録
内容記述 Chiral supramolecular boron Lewis acid catalysts were prepared from chiral 3-phosphoryl-1,1′-bi-2-naphthols, (2-cyanophenyl)boronic acids, and tris(pentafluorophenyl)borane, bound through CN···B and PO···B coordination bonds. In particular, the coordinated tris(pentafluorophenyl)boranes increase the Lewis acidity of the active center in the manner of a Lewis acid assisted Lewis acid catalyst system. A possible cavity in these catalysts was highly suitable for several Diels–Alder probe reactions of acroleins with cyclic or acyclic dienes, which gave the corresponding adducts in good to high yields and high enantio­selectivities.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 Georg Thieme Verlag
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1055/s-0035-1561362
ISSN
収録物識別子タイプ PISSN
収録物識別子 0936-5214
書誌情報 en : Synlett

巻 27, 号 7, p. 1061-1067, 発行日 2016-04
著者版フラグ
値 author
URI
識別子 http://doi.org/10.1055/s-0035-1561362
識別子タイプ DOI
URI
識別子 http://hdl.handle.net/2237/25400
識別子タイプ HDL
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