{"_buckets": {"deposit": "11537552-6749-4b5e-a1f8-305e12b4a79d"}, "_deposit": {"id": "23541", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "23541"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00023541", "sets": ["696"]}, "author_link": ["69925", "69926", "69927", "69928", "69929", "69930", "69931", "69932", "69933"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2016-12-12", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "50", "bibliographicPageEnd": "15636", "bibliographicPageStart": "15633", "bibliographicVolumeNumber": "55", "bibliographic_titles": [{"bibliographic_title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The Mo nitrogenase catalyzes the ambient reduction of N2 to NH3 at its M-cluster site. A complex metallocofactor with a core composition of [MoFe7S9C], the M-cluster, can be extracted from the protein scaffold and used to facilitate the catalytic reduction of CN−, CO, and CO2 into hydrocarbons in the isolated state. Herein, we report the synthesis, structure, and reactivity of an asymmetric M-cluster analogue with a core composition of [MoFe5S9]. This analogue, referred to as the Mo-cluster, is the first synthetic example of an M-cluster mimic with Fe and Mo positioned at opposite ends of the cluster. Moreover, the ability of the Mo-cluster to reduce C1 substrates to hydrocarbons suggests the feasibility of developing nitrogenase-based biomimetic approaches to recycle C1 waste into fuel products.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://doi.org/10.1002/anie.201608806"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/25738"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/anie.201608806", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "This is the peer reviewed version of the following article: [K. Tanifuji, N. Sickerman, C. C. Lee, T. Nagasawa, K. Miyazaki, Y. Ohki, K. Tatsumi, Y. Hu, M. W. Ribbe, Angew. Chem. Int. Ed. 2016, 55, 15633.], which has been published in final form at [http://doi.org/10.1002/anie.201608806]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1433-7851", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Tanifuji, Kazuki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "69925", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sickerman, Nathaniel", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "69926", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Lee, Chi Chung", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "69927", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nagasawa, Takayuki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "69928", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Miyazaki, Kosuke", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "69929", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ohki, Yasuhiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "69930", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tatsumi, Kazuyuki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "69931", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hu, Yilin", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "69932", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ribbe, Markus W.", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "69933", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-12-12"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "ACIE2016.pdf", "filesize": [{"value": "1.5 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 1500000.0, "url": {"label": "ACIE2016.pdf ファイル公開：2017/12/12", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/23541/files/ACIE2016.pdf"}, "version_id": "dd3c4bfe-eb7d-44a1-83f5-05f4bfbfd183"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["696"], "permalink_uri": "http://hdl.handle.net/2237/25738", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2017-03-21"}, "publish_date": "2017-03-21", "publish_status": "0", "recid": "23541", "relation": {}, "relation_version_is_last": true, "title": ["Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor"], "weko_shared_id": -1}