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Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor
http://hdl.handle.net/2237/25738
http://hdl.handle.net/2237/257383fff676d-f988-4f84-a494-958000ad6275
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
ACIE2016.pdf ファイル公開：2017/12/12 (1.5 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2017-03-21 | |||||
| タイトル | ||||||
| タイトル | Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor | |||||
| 言語 | en | |||||
| 著者 |
Tanifuji, Kazuki
× Tanifuji, Kazuki× Sickerman, Nathaniel× Lee, Chi Chung× Nagasawa, Takayuki× Miyazaki, Kosuke× Ohki, Yasuhiro× Tatsumi, Kazuyuki× Hu, Yilin× Ribbe, Markus W. |
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| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 権利 | ||||||
| 言語 | en | |||||
| 権利情報 | This is the peer reviewed version of the following article: [K. Tanifuji, N. Sickerman, C. C. Lee, T. Nagasawa, K. Miyazaki, Y. Ohki, K. Tatsumi, Y. Hu, M. W. Ribbe, Angew. Chem. Int. Ed. 2016, 55, 15633.], which has been published in final form at [http://doi.org/10.1002/anie.201608806]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The Mo nitrogenase catalyzes the ambient reduction of N2 to NH3 at its M-cluster site. A complex metallocofactor with a core composition of [MoFe7S9C], the M-cluster, can be extracted from the protein scaffold and used to facilitate the catalytic reduction of CN−, CO, and CO2 into hydrocarbons in the isolated state. Herein, we report the synthesis, structure, and reactivity of an asymmetric M-cluster analogue with a core composition of [MoFe5S9]. This analogue, referred to as the Mo-cluster, is the first synthetic example of an M-cluster mimic with Fe and Mo positioned at opposite ends of the cluster. Moreover, the ability of the Mo-cluster to reduce C1 substrates to hydrocarbons suggests the feasibility of developing nitrogenase-based biomimetic approaches to recycle C1 waste into fuel products. | |||||
| 言語 | en | |||||
| 出版者 | ||||||
| 出版者 | Wiley | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | journal article | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1002/anie.201608806 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 1433-7851 | |||||
| 書誌情報 |
en : ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 巻 55, 号 50, p. 15633-15636, 発行日 2016-12-12 |
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| 著者版フラグ | ||||||
| 値 | author | |||||
| URI | ||||||
| 識別子 | http://doi.org/10.1002/anie.201608806 | |||||
| 識別子タイプ | DOI | |||||
| URI | ||||||
| 識別子 | http://hdl.handle.net/2237/25738 | |||||
| 識別子タイプ | HDL | |||||
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Tanifuji, Kazuki, Sickerman, Nathaniel, Lee, Chi Chung, Nagasawa, Takayuki, Miyazaki, Kosuke, Ohki, Yasuhiro, Tatsumi, Kazuyuki, Hu, Yilin, Ribbe, Markus W., 2016, Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor: Wiley, 15633–15636 p.
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