{"_buckets": {"deposit": "f75effcd-903e-4e99-be56-2adbe887ac93"}, "_deposit": {"id": "24033", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "24033"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00024033"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2017-02-15", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "238", "bibliographicPageStart": "230", "bibliographicVolumeNumber": "335", "bibliographic_titles": [{"bibliographic_title": "Journal of Photochemistry and Photobiology A: Chemistry"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Five anthocyanins, namely, pelargonidin, cyanidin, delphinidin, petunidin and malvidin 3-O-glucosides, possessing different substitution patterns in the B-ring of the anthocyanidin chromophore were isolated from various plant materials. Dye-sensitized solar cells (DSSCs) were fabricated using the pure pigments, and then their cell colors and conversion efficiencies (\u03b7%) were compared. After optimization of the fabrication conditions, all the cells showed 0.6\u20131.4% conversion efficiency under AM 1.5. Among them, petunidin 3-O-glucoside provided the highest efficiency of 1.42% following the addition of deoxycholic acid (DCA) as an additive; however, removal of the glucosyl unit decreased the efficiency. The cell colors of cyanidin, delphinidin, and petunidin 3-O-glucosides appeared bluer with relatively high \u03b7% (\u003e1%) values compared with those of pelargonidin and malvidin 3-O-glucosides. These phenomena may indicate that the former three pigments may attach to TiO2 through the catechol moiety of the B-ring of the chromophores. Time-dependent density functional theory (TD-DFT) calculations were performed on model systems consisting of anthocyanidin dyes on a (TiO2)38 cluster to characterize the photo-absorption properties of DSSCs.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "https://doi.org/10.1016/j.jphotochem.2016.12.005"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/26249"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Elsevier"}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u00a9 2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1010-6030", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kimura, Yuki"}], "nameIdentifiers": [{"nameIdentifier": "71340", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Maeda, Takeshi"}], "nameIdentifiers": [{"nameIdentifier": "71341", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Iuchi, Satoru"}], "nameIdentifiers": [{"nameIdentifier": "71342", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Koga, Nobuaki"}], "nameIdentifiers": [{"nameIdentifier": "71343", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Murata, Yasujiro"}], "nameIdentifiers": [{"nameIdentifier": "71344", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Wakamiya, Atsushi"}], "nameIdentifiers": [{"nameIdentifier": "71345", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yoshida, Kumi"}], "nameIdentifiers": [{"nameIdentifier": "71346", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-02-15"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "JPHOTOCHEM_2016_803_Revision1_V0.pdf", "filesize": [{"value": "5.9 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 5900000.0, "url": {"label": "JPHOTOCHEM_2016_803_Revision1_V0.pdf \u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2019/02/15", "url": "https://nagoya.repo.nii.ac.jp/record/24033/files/JPHOTOCHEM_2016_803_Revision1_V0.pdf"}, "version_id": "d8a76b45-a38a-4afe-a4dd-513071c877e5"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Anthocyanin", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Dye-sensitized solar cell", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Natural pigment", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Petunidin 3-O-glucoside", "subitem_subject_scheme": "Other"}, {"subitem_subject": "TD-DFT calculation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "(TiO2)38 cluster", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Characterization of dye-sensitized solar cells using five pure anthocyanidin 3-O-glucosides possessing different chromophores", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Characterization of dye-sensitized solar cells using five pure anthocyanidin 3-O-glucosides possessing different chromophores"}]}, "item_type_id": "10", "owner": "1", "path": ["312/313/314"], "permalink_uri": "http://hdl.handle.net/2237/26249", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2017-05-09"}, "publish_date": "2017-05-09", "publish_status": "0", "recid": "24033", "relation": {}, "relation_version_is_last": true, "title": ["Characterization of dye-sensitized solar cells using five pure anthocyanidin 3-O-glucosides possessing different chromophores"], "weko_shared_id": null}